|
OALib Journal期刊
ISSN: 2333-9721
费用：99美元
|
|
|
|
氩吸附法研究多级孔分子筛的孔结构
, PP. 379-384
Keywords: 氩吸附,多级孔分子筛,孔结构,介孔
Abstract:
？采用不同方法分别制备了双介孔分子筛、介微孔分子筛及介孔沸石材料,利用氩吸附法并结合xrd技术表征了多级孔分子筛的孔结构。探讨了适用于多级孔分子筛的孔径分布计算方法,揭示了不同类型吸附等温线与孔径分布、孔型及孔容等之间的关系。研究表明,对于多级孔分子筛、微孔和介孔的孔径分布分别用sf法和bjh法计算较适宜,全孔分析可用nldft法计算。通过对ts-1介孔沸石的孔结构分析发现,tpaoh在改性制备介孔ts-1的过程中起到了生成介孔及促进二次晶化的双重作用。
| [1] | 王亚军,唐颐,王星东,杨武利,倪铮,华伟明,乐英红,高滋.具有微孔/大孔双孔道体系沸石材料的合成[j].高等学校化学学报,2000,21(7):1013-1015.(wangya-jun,tangyi,wangxing-dong,yangwu-li,nizheng,huawei-ming,yueying-hong,gaozi.synthesisofsilicatematerialswithmicro/macroporousbimodalporesystems[j].chemjchinuniv,2000,21(7):1013-1015.)
|
| [2] | 李福祥,吴岚,秦梦庚,窦涛,钟炳.中孔mcm-41分子筛在微孔沸石zsm-5上附晶生长的研究[j].燃料化学学报,1998,26(2):7-12.(lifu-xiang,wulan,qinmeng-geng,doutao,zhongbing.overgrowthofmesoporousmcm-41onzeolitezsm-5[j].jfuelchemtechnol,1998,26(2):7-12.)
|
| [3] | everettdh.iniupacmannulofsymbolsandterminology[j].pureapplchem,1972,31(4):578-638.
|
| [4] | xiaofs,hany,yuy,mengxj,yangm,wus.hydrothermallystableorderedmesoporoustitanosilicateswithhighlyactivecatalyticsites[j].jamchemsoc,2002,124(6):888-889.
|
| [5] | huanglm,guowp,dengp,xuezy,liqz.investigationofsynthesizingmcm-41/zsm-5composites[j].jphyschemb,2000,104(13):2817-2823.
|
| [6] | jagielloj,thommesm.comparisonofdftcharacterizationmethodsbasedonn2,ar,co2,andh2adsorptionappliedtocarbonswithvariousporesizedistributions[j].carbon,2004,42(7):1227-1232.
|
| [7] | 杨正红,高原.含有微孔的多孔固体材料的比表面测定[j].现代科学仪器,2010,1:97-102.(yangzheng-hong,gaoyuan.betsurfaceareaanalysisonmicroporousmaterials[j].modsciinstrum,2010,1:97-102.)
|
| [8] | liulp,xiongg,wangxs,chengxj.synthesisofnanosizedalkit-1mesoporousmolecularsieveanditscatalyticperformancefortheconversionof1,2,4-trimethylbenzene[j].catallett,2011,141(8):1136-1141.
|
| [9] | liulp,xiongg,wangxs,caij,zhaoz.directsynthesisofdisorderedmicro-mesoporousmolecularsieve[j].microporousmesoporousmater,2009,123(1/3):221-227.
|
| [10] | ryoor,kimjm,koch,shinch.disorderedmolecularsievewithbranchedmesoporouschannelnetwork[j].jphyschem,1996,100(45):17718-17721.
|
| [11] | 徐如人,庞文琴,于吉红,霍启升,陈接胜.分子筛与多孔材料化学[m].北京:科学出版社,2004.(xuru-ren,pangwen-qin,yuji-hong,huoqi-sheng,chenjie-sheng.chemistry-zeolitesandporousmaterials[m].beijing:sciencepress,2004.)
|
| [12] | wangyr,linm,tuela.hollowts-1crystalsformedviaadissolution-recrystallizationprocess[j].microporousmesoporousmater,2007,102(1/3):80-85.
|
| [13] | vangriekenr,sotelojl,menendezjm,meleroja.anomalouscrystallizationmechanisminthesynthesisofnanocrystallinezsm-5[j].microporousmesoporousmater,2000,39(1/2):135-147.
|
| [14] | bonillag,díazi,jeonghk,jeonghk,leey,viachosdg.zeolite(mfi)crystalmorphologycontrolusingorganicstructuredirectingagents[j].chemmater,2004,16(26):5697-5705.
|
Full-Text
|
|
Contact Us
service@oalib.com QQ:3279437679 
WhatsApp +8615387084133
|
|
