OALib Journal期刊
ISSN: 2333-9721
费用:99美元
|
|
|
大气压下甲烷火花放电制乙炔和合成气
, PP. 235-242
Keywords: 甲烷,火花放电,二氧化碳,合成气,发射光谱
Abstract:
?用大气压下火花放电方法和发射光谱原位诊断技术,对ch4直接转化制乙炔和间接转化制合成气进行了研究,并与介质阻挡放电进行了比较。结果表明,火花放电具有能量效率高的突出优点,能够高效地将ch4活化成c原子、h原子和c2等活泼物种。当ch4单独进料时,能得到以c2h2为主的烃类产物。当ch4与co2和o2共进料时,能得到h2/co比值可调的合成气产物。在用火花放电转化ch4和co2制合成气时,添加o2能够避免反应器的结炭问题,反应温度只需225℃,与常规催化法相比具有明显的低温优势。
References
[1] | 余长林,胡久彪,杨凯,周晓春.制备方法对ni/ceo2-al2o3催化剂甲烷部分氧化催化性能的影响[j].燃料化学学报,2013,41(6):722-728.(yuchang-lin,hujiu-biao,yangkai,zhouxiao-chun.effectsofpreparationmethodsonthecatalyticperformanceofni/ceo2-al2o3catalystinmethanepartialoxidation[j].jfuelchemtechnol,2013,41(6):722-728.)
|
[2] | hornr,williamska,degensteinnj,schmidtld.syngasbycatalyticpartialoxidationofmethaneonrhodium:mechanisticconclusionsfromspatiallyresolvedmeasurementsandnumericalsimulations[j].jcatal,2006,242(1):92-102.
|
[3] | 郭章龙,黄丽琼,储伟,罗仕忠.助剂对nimgal催化剂的结构和甲烷二氧化碳重整反应性能的影响[j].物理化学学报,2014,30(4):723-728.(guozhang-long,huangli-qiong,chuwei,luoshi-zhong,effectsofpromoteronnimgalcatalyststructureandperformanceforcarbondioxidereformingofmethane[j].actaphy-chimsin,2014,30(4):723-728.)
|
[4] | choudharyvr,mondalkc,mullasar.conversionofmethaneandmethanolintogasolineoverbifunctionalga-,zn-,in-,and/ormo-modifiedzsm-5zeolites[j].angewcheminted,2005,44(28):4381-4385.
|
[5] | 吕静,李振花,王保伟,许根慧.反应器型式对甲烷低温等离子体转化制c2烃的影响[j].燃料化学学报,2005,33(6):755-759.(lvjing,lizhen-hua,wangbao-wei,xugen-hui.effectofreactortypeonmethaneconversiontoc2hydrocarbonsbylowtemperatureplasma[j].jfuelchemtechnol,2005,33(6):755-759.)
|
[6] | 周军成,尹燕华,郑邯勇,周旭,徐月,龚俊松,张龙龙,宋光涛.甲烷氧等离子体直接合成过氧化氢[j].高等学校化学学报,2011,32(10):2240-2242.(zhoujun-cheng,yinyan-hua,zhenghan-yong,zhouxu,xuyue,gongjun-song,zhanglong-long,songguang-tao.directsynthesisofh2o2usingmethane-oxygenplasma[j].chemjchinuniv,2011,32(10):2240-2242.)
|
[7] | 董洁,王丽,赵越,张家良,郭洪臣.添加气对非平衡等离子体转化低碳烷烃的影响[j].高等学校化学学报,2013,34(1):192-197.(dongjie,wangli,zhaoyue,zhangjia-liang,guohong-chen.effectofadditivegasesonlightalkanesconvertingunderdielectricbarrierdischarge[j].chemjchinuniv,2013,34(1):192-197.)
|
[8] | liucj,mallinsonr,lobbanl.comparativeinvestigationsonplasmacatalyticmethaneconversiontohigherhydrocarbonsoverzeolites[j].applcatala:gen,1999,178(1):17-27.
|
[9] | indartoa,choijw,leeh,songhk.effectofadditivegasesonmethaneconversionusingglidingarcdischarge[j].energy,2006,31(14):2986-2995.
|
[10] | shencs,sundk,yanghs.methanecouplinginmicrowaveplasmaunderatmosphericpressure[j].jnatgaschem,2011,20(4):449-456.
|
[11] | moshrefimm,rashidif.hydrogenproductionfrommethanebydcsparkdischarge:effectofcurrentandvoltage[j].jnatgasscieng,2014,16:85-89.
|
[12] | aleknaviciutei,karayiannistg,collinsmw,xanthosc.methanedecompositionunderacoronadischargetogeneratecox-freehydrogen[j].energy,2013,59(15):432-439.
|
[13] | xuc,tux.plasma-assistedmethaneconversioninanatmosphericpressuredielectricbarrierdischargereactor[j].jenergychem,2013,22(3):420-425.
|
[14] | lixs,shic,wangkj,zhangxl,xuy,zhuam.highyieldofaromaticsfromch4inaplasma-followed-by-catalyst(pfc)reactor[j].aichej,2006,52(9):3321-3324.
|
[15] | muhammadam,davidh,areejm,shux,karlh.schoenbach.studyoftheproductionofhydrogenandlighthydrocarbonsbysparkdischargesindiesel,kerosene,gasoline,andmethane[j].plasmachemplasmap,2013,33(1):271-279.
|
[16] | moshrefimm,rashidif,bozrogzadehhr,haghighime.dryreformingofmethanebydcsparkdischargewitharotatingelectrode[j].plasmachemplasmap,2013,33(2):453-466.
|
[17] | kados,urasakik,sekiney,fujimotok,nozakit,okazakik.reactionmechanismofmethaneactivationusingnon-equilibriumpulseddischargeatroomtemperature[j].fuel,2003,82(18):2291-2297.
|
[18] | christophedb,bertv,tomm,janvd,sabinep,annemieb.fluidmodelingoftheconversionofmethaneintohigherhydrocarbonsinanatmosphericpressuredielectricbarrierdischarge[j].plasmaprocesspolym,2011,8(11):1033-1058.
|
[19] | wangkj,lixs,zhuam.agreenprocessforhigh-concentrationethyleneandhydrogenproductionfrommethaneinaplasma-followed-by-catalystreactor[j].plasmascitechnol,2011,13(1):77-81.
|
[20] | sentekj,krawczykk,mlotekm,kalczewskam,krokert,kolbt,schenka,gerickekh,schmidtsk.plasma-catalyticmethaneconversionwithcarbondioxideindielectricbarrierdischarges[j].applcatalb:environ,2010,94(1/2):19-26.
|
[21] | wangq,shihl,yanbh,jiny,cengy.steamenhancedcarbondioxidereformingofmethaneindbdplasmareactor[j].intjhydrogenenergy,2011,36(14):8301-8306.
|
[22] | zhangxm,chams.electron-induceddryreformingofmethaneinatemperature-controlleddielectricbarrierdischargereactor[j].jphysd:applphys,2013,46(41):415205.
|
[23] | taekk,wongl.reactionbetweenmethaneandcarbondioxidetoproducesyngasindielectricbarrierdischargesystem[j].jindengchem,2012,18(5):1710-1714.
|
[24] | heintzem,magureanum,kettlitzm.mechanismofc2hydrocarbonformationfrommethaneinapulsedmicrowaveplasma[j].japplphys,2002,92(12):7022-7031.
|
[25] | pearserwb,gayconag.identificationofmolecularspectra[m].chapmanandhall:london,1965:82-83.
|
[26] | harilalss,issacrc,bindhucv,nampoorivpn,vallabhancpg.opticalemissionstudiesofspeciesinlaser-producedplasmafromcarbon[j].jphysd:applphys,1997,30(12):1703-1709.
|
[27] | janevrk,reiterd.collisionprocessesofchyandchy+hydrocarbonswithplasmaelectronsandprotons[j].physplasmas,2002,9:4071-4081.
|
[28] | horacekj,cizekm,houfekk,kolorencp,domckew.dissociativeelectronattachmentandvibrationalexcitationofh2bylow-energyelectrons:calculationsbasedonanimprovednonlocalresonancemodel.ii.vibrationalexcitation[j].physreva,2006,73(2):022701.
|
[29] | naitos,ikedam,iton,hattorit,gotot.effectofraregasdilutiononch3radicaldensityinrf-dischargech4plasma[j].jpnjapplphys,1993,32(12a):5721-5725.
|
[30] | ichikaway,teiis.molecularionandmetastableatomformationsandtheireffectsontheelectrontemperatureinmedium-pressurerare-gaspositive-columnplasmas[j].jphysd:applphys,1980,13(11):2031-2043.
|
[31] | mcconkeyjw,malonecp,johnsonpv,winsteadc,mckoyv,kaniki.electronimpactdissociationofoxygen-containingmolecules-acriticalreview[j].physrep,2008,466(1/3):1-103.
|
[32] | steenml,butoici,fisherer.identificationofgas-phasereactivespeciesandchemicalmechanismsoccurringatplasma-polymersurfaceinterfaces[j].langmuir,2001,17(26):8156-8166.
|
Full-Text
|
|
Contact Us
service@oalib.com QQ:3279437679 
WhatsApp +8615387084133
|
|