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n-butyl-pyridiniumtetrafluoroborateasahighlyefficientionicliquidforremovalofdibenzothiophenefromorganicsolutions

, PP. 195-201

Keywords: extraction,desulfurization,ionicliquids,dibenzothiophene

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Abstract:

?inthisresearch,1-butyl-pyridiniumtetrafluoroborate([c4py][bf4]-)waspreparedbyionexchangemethodandwascharacterizedby1h-nmr,13c-nmr,andft-irtechniques.thesynthesizedionicliquidwasusedforremovalofdibenzothiopheneasatypicalorganosulfurpollutantfromorganicmedium.theeffectofdifferentparametersontheextractionefficiencywasstudiedandoptimized.attheoptimizedconditions,97.68%ofdibenzothiophenewasextractedfrom1000mg/ln-hexanesolution.theextractionefficiencyobtainedinthisworkwashigherthanthepreviousreportedvalues.thedesulfurizationreactionwaskineticallyfollowedthesecondordermechanism.theionicliquidwasreusableandafterfourregenerationcycles97%ofitsoriginalextractionefficiencywasretained.

References

[1]  zhail,zhongc,hejl.hydroxylammoniumionicliquidssynthesizedbywater-bathmicrowave:synthesisanddesulfurization[j].jhazardmater,2010,177(1/3):807-813.
[2]  wilfardc,kiatc,manz,bustamm,ibrahimm,mutalibm,phakz.extractionofdibenzothiophenefromdodecaneusingionicliquids[j].fuelprocesstechnol,2012,93(1):85-89.
[3]  jiangx,niey,lic,wangz.imidazolium-basedalkylphosphateionicliquids-apotentialsolventforextractivedesulfurizationoffuel[j].fuel,2008,87(1):79-84.
[4]  liusz,wangbh,cuibc,sunll.deepdesulfurizationofdieseloiloxidizedbyfe(vi)systems[j].fuel,2008,87(3):422-428.
[5]  jiangzx,l譈hy,zhangyn,lic.oxidativedesulfurizationoffueloils[j].chinjcatal,2011,32(5):707-715.
[6]  zhangc,panx,wangf,liux.extraction-oxidationdesulfurizationbypyridinium-basedtask-specificionicliquids[j].fuel,2012,102:580-584.
[7]  zhangc,wangf,panxy,liuxq.studyofextraction-oxidationdesulfurizationofmodeloilbyacidicionicliquid[j].jfuelchemtechnol,2011,39(9):689-693.
[8]  arcea,franciscom,sotoa.evaluationofthepolysubstitutedpyridiniumionicliquid[hmmpy][ntf2]asasuitablesolventfordesulfurization:phaseequilibria[j].jchemthermodyn,2010,42(6):712-718.
[9]  luebm,guoz,xuxb.high-performanceliquidchromatographyanalysismethodsdevelopedforquantifyingenzymaticesterificationofflavonoidsinionicliquids[j].jchromatogr,2008,1198-1199:107-114.
[10]  meindersmagw,podta,dehaanab.selectionofionicliquidsfortheextractionofaromatichydrocarbonsfromaromatic/aliphaticmixtures[j].fuelprocesstechnol,2005,87(1):59-70.
[11]  galerj,gilbertb,osteryoungra.ramanspectraofmoltenaluminumchloride:1-butylpyridiniumchloridesystemsatambienttemperatures[j].inorgchem,1978,17(10):2728-2729.
[12]  niey,lic,mengh,wangzn.n-dialkylimidazoliumdialkylphosphateionicliquids:theirextractiveperformanceforthiopheneseriescompoundsfromfueloilsversusthelengthofalkylgroup[j].fuelprocesstechnol,2008,89(10):978-983.
[13]  meih,meibw,yenft.anewmethodforobtainingultra-lowsulfurdieselfuelviaultrasoundassistedoxidativedesulfurization[j].fuel,2003,82(4):405-414.
[14]  rothm.partitioningbehaviouroforganiccompoundsbetweenionicliquidsandsupercriticalfluids[j].jchromatogra,2009,1216(10):1861-1880.
[15]  visserae,rogersrd.room-temperatureionicliquids:newsolventsforf-elementseparationsandassociatedsolutionchemistry[j].jsolidstatechem,2003,171(1/2):109-113.
[16]  lift,koucg,sunzm,haoyj,liurh,zhaods.deepextractiveandoxidativedesulfurizationofdibenzothiophenewithc5h9no·sncl2coordinatedionicliquid[j].jhazarmater,2012,205:164-170.
[17]  franciscom,arcea,sotoa.ionicliquidsondesulfurizationoffueloils[j].fluidphaseequilib,2010,294(1/2):39-48.
[18]  calvarn,dominguezi,gómeze,dominguezá.domínguez,separationofbinarymixturesaromatic+aliphaticusingionicliquids:influenceofthestructureoftheionicliquid,aromaticandaliphatic[j].chemengj,2011,175:213-221.
[19]  chuxm,huyf,lijg,liangqq,liuys,zhagnxm,pengxm,yuewj.desulfurizationofdieselfuelbyextractionwith[bf4]-basedionicliquids[j].chinjchemeng,2008,16(6):881-884.
[20]  khupsend,kumara.ionicliquids:newmaterialswithwideapplications[j].indianjchemsecta,2010,49(5/6):635-648.
[21]  wangjl,zhaods,zhouep,dongz.desulfurizationofgasolinebyextractionwithn-alkyl-pyridinium-basedionicliquids[j].jfuelchemtechnol,2007,35(3):293-296.
[22]  fangd,chengj,gongk,shiqr,zhouxl,liuzl.greenandnovelprocedureforthepreparationofionicliquid[j].jfluorinechem,2008,129(2):108-111.

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