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OALib Journal期刊
ISSN: 2333-9721
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以四甲基铵硅酸盐为柱化剂合成层柱状mcm-36分子筛
, PP. 858-864
Keywords: 层柱状分子筛,mcm-36,柱化剂,水热合成,表征
Abstract:
？以层状mcm-22p为前驱体，四甲基铵硅酸盐为柱化剂，采用动态水热法考察了mcm-36分子筛的合成条件，并通过xrd、n2物理吸附、tem、27al-masnmr以及nh3-tpd等手段对合成分子筛进行了表征。结果表明，与传统的采用正硅酸乙酯为柱化剂的柱化过程相比，以四甲基铵硅酸盐为柱化剂时，已溶胀的前驱体不经干燥处理即可直接在含水体系进行柱化插层合成得到层间距均一的层柱状mcm-36分子筛，适宜的合成条件为：先在80℃的高ph值（约13.5）环境下对前驱体溶胀24h，然后在100℃下柱化插层24h。表征结果表明，mcm-36分子筛具有层内微孔和层间介孔的复合孔道结构以及较大的比表面积（特别是外比表面积）；与hmcm-22相比，hmcm-36的表面酸性虽明显降低，但其层间介孔结构的形成使大量b酸中心暴露于大分子易于接近的层间介孔孔壁，可为涉及较大分子的催化反应提供更多可接近的活性位中心。
| [1] | rothwj,dorsetdl.expandedviewofzeolitestructuresandtheirvariabilitybasedonlayerednatureof3-dframeworks[j].micropormesopormater,2011,142(1):32-36.
|
| [2] | rothwj,kresgect,vartulijc,leonowiczme,fungas,mccullensb.mcm-36:thefirstpillaredmolecularsievewithzeoliteproperties[j].studsurfscicatal,1995,94:301-308.
|
| [3] | rothwj.synthesisofdelaminatedandpillaredzeoliticmaterials[j].studsurfscicatal,2007,168:221-239.
|
| [4] | maheshwaris,jordane,kumars,batesfs,leepennr,shantzdf,tsapatsism.layerstructurepreservationduringswelling,pillaring,andexfoliationofazeoliteprecursor[j].jamchemsoc,2008,130(4):1507-1516.
|
| [5] | cormaa,fornesv,martinez-trigueroj,perghersb.delaminatedzeolites:combiningthebenefitsofzeolitesandmesoporousmaterialsforcatalyticuses[j].jcatal,1999,186(1):57-63.
|
| [6] | heyj,nivarthygs,ederf,seshank,lercherja.synthesis,characterizationandcatalyticactivityofthepillaredmolecularsievemcm-36[j].micropormesopormater,1998,25(1/3):207-224.
|
| [7] | 张祚望,张钰,王振旅,邢海军,贾明君,吴通好,张文祥.h-mcm-22和h-mcm-36分子筛对苯与异丙醇烷基化反应的催化性能[j].催化学报,2008,29(10):1015-1020.(zhangzuo-wang,zhangyu,wangzhen-lü,xinghai-jun,jiaming-jun,wutong-hao,zhangwen-xiang.catalyticperformanceofh-mcm-22andh-mcm-36zeolitesforalkylationofbenzenewithisopropanol[j].chinesejournalofcatalysis,2008,29(10):1015-1020.)
|
| [8] | lacarrierea,luckf,swierczynskiad,fajulaf,huleav.methanoltohydrocarbonsoverzeoliteswithmwwtopology:effectofzeolitetextureandacidity[j].applcatala:gen,2011,402(1/2):208-217.
|
| [9] | brndlem,sauerj.aciditydifferencesbetweeninorganicsolidsinducedbytheirframeworkstructure.acombinedquantummechanics/molecularmechanicsabinitiostudyonzeolites[j].jamchemsoc,1998,120(7):1556-1570.
|
| [10] | 徐如人,庞文琴,于吉红.分子筛与多孔材料化学[m].北京:科学出版社,2004.(xuru-ren,pangwen-qin,yuji-hong.zeolitesandporousmaterials[m].beijing:sciencepress,2004.)
|
| [11] | 凌云,郑玉婷,刘月明,王振东,吴海虹,吴鹏.微波辅助晶化法合成mcm-22分子筛的研究[j].化学学报,2010,68(20):2035-2040.(lingyun,zhengyu-ting,liuyue-ming,wangzhen-dong,wuhai-hong,wupeng.astudyonmicrowave-assistedsynthesisofmcm-22zeolite[j].actachimicasinica,2010,68(20):2035-2040.)
|
| [12] | liugq,jiangjg,yangbt,fangxq,xuh,penghg,xul,liuym,wup.hydrothermalsynthesisofmww-typestannosilicateanditspost-structuraltransformationtomcm-56analogue[j].micropormesopormater,2013,165(1):210-218.
|
| [13] | 张君涛,郝娜娜,王妮.zsm-5/mcm-41复合分子筛的合成与表征[j].燃料化学学报,2013,41(10):1267-1273.(zhangjun-tao,haona-na,wangni.synthesisandcharacterizationofzsm-5/mcm-41compositemolecularsieves[j].journaloffuelchemistryandtechnology,2013,41(10):1267-1273.)
|
| [14] | chlubnáp,rothwj,zukala,kubum,pavlatováj.pillaredmwwzeolitesmcm-36preparedbyswellingmcm-22pinconcentratedsurfactantsolutions[j].cataltoday,2012,179(1):35-42.
|
| [15] | leonowiczme,lawtonja,lawtonsl,rubinmk.mcm-22-amolecularsievewithtwoindependentmultidimensionchannelsystems[j].science,1994,264(5167):1910-1913.
|
| [16] | cormaa,corellc,pérez-parientej.synthesisandcharacterizationofthemcm-22zeolite[j].zeolites,1995,15(1):2-8.
|
| [17] | rothwj,dorsetdl,kennedygj.discoveryofnewmwwfamilyzeoliteemm-10:identificationofemm-10pasthemissingmwwprecursorwithdisorderedlayers[j].micropormesopormater,2011,142(1):168-177.
|
| [18] | zhangy,xinghj,yangpp,wup,jiamj,sunjz,wuth.alkylationofbenzenewithpropyleneovermcm-36:acomparativestudywithmcm-22zeolitesynthesizedfromthesameprecursors[j].reactkinetcatallett,2007,90(1):45-52.
|
| [19] | rothwj,vartulijc.preparationofexfoliatedzeolitesfromlayeredprecursors:theroleofphandnatureofintercalatingmedia[j].studsurfscicatal,2002,141:273-279.
|
| [20] | barthj-o,jentysa,kornatowskij,lercherja.controlofacid-basepropertiesofnewnanocompositederivativesofmcm-36bymixedoxidepillaring[j].chemmater,2004,16(4):724-730.
|
| [21] | 王保玉,吴建梅,李牛,袁忠勇,项寿鹤.超声作用下mcm-36分子筛的快速合成[j].催化学报,2007,28(5):398-400.(wangbao-yu,wujian-mei,liniu,yuanzhong-yong,xiangshou-he.rapidsynthesisofmcm-36zeoliteunderultrasonictreatment[j].chinesejournalofcatalysis,2007,28(5):398-400.)
|
| [22] | kimsy,banhj,ahnws.ti-mcm-36:anewmesoporousepoxidationcatalyst[j].catallett,2007,113(3/4):160-164.
|
| [23] | maheshwaris,martinezc,portillamt,llopisfj,cormaa,tsapatsism.influenceoflayerstructurepreservationonthecatalyticpropertiesofthepillaredzeolitemcm-36[j].jcatal,2010,272(2):298-308.
|
| [24] | cormaa,corellc,pérez-parietej,guiljm,guil-lópezr,nicolopouloss,gonzalezcalbetj,vallet-regim.adsorptionandcatalyticpropertiesofmcm-22:theinfluenceofzeolitestructure[j].zeolites,1996,16(1):7-14.
|
| [25] | degnanjrtf,morrissmithc,venkatcr.alkylationofaromaticswithethyleneandpropylene:recentdevelopmentsincommercialprocesses[j].applcatala:gen,2001,221(1/2):283-294.
|
| [26] | cejkaj,krejcía,?ilkován,kotrlaj,ernsts,webera.activityandselectivityofzeolitesmcm-22andmcm-58inthealkylationoftoluenewithpropylene[j].micropormesopormater,2002,53(1/3):121-133.
|
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