|
OALib Journal期刊
ISSN: 2333-9721
费用：99美元
|
|
|
|
委内瑞拉减渣供氢热转化中沥青质结构变化研究
, PP. 1064-1069
Keywords: 沥青质,热转化,平均相对分子质量,元素组成,平均结构参数
Abstract:
？以委内瑞拉减压渣油为原料,在高压反应釜内考察了反应温度425℃时不同反应时间下常规热转化与供氢热转化反应前后沥青质的平均相对分子质量、元素组成、氢类型分布及其平均结构参数变化。结果表明,与常规热转化相比,反应时间相同时,供氢热转化过程所得残渣油沥青质平均相对分子质量较低,s/c原子比较低,而h/c原子比及活泼性氢量较高。供氢剂能够在热转化过程中降低残渣油沥青质的芳碳率,提高其环烷碳率及环烷环与芳香环的比值,从而延缓其相分离及生焦过程。
| [1] | 王齐,王宗贤,沐宝泉.委内瑞拉常压渣油供氢热转化研究[j].燃料化学学报,2012,40(10):1200-1205.(wangqi,wangzong-xian,mubao-quan.hydrogendonorvisbreakingofvenezuelanatmosphericresidue[j].journaloffuelchemistryandtechnology,2012,40(10):1200-1205.)
|
| [2] | 王齐,郭磊,王宗贤.委内瑞拉减压渣油供氢热转化基础研究[j].燃料化学学报,2012,40(11):1317-1322.(wangqi,guolei,wangzong-xian.hydrogendonorvisbreakingofvenezuelanvacuumresidue[j].journaloffuelchemistryandtechnology,2012,40(11):1317-1322.)
|
| [3] | 梁文杰.石油化学[m].东营:中国石油大学出版社,2009.(liangwen-jie.petroleumchemistry[m].dongying:chinauniversityofpetroleumpress,2009.)
|
| [4] | 王宗贤,何岩,郭爱军.辽河和孤岛渣油供氢与生焦趋势[j].燃料化学学报,1999,27(3):251-255.(wangzong-xian,heyan,guoai-jun.studyonhydrogen-donatingabilityofvacuumresiduesandtheirsubfractions[j].journaloffuelchemistryandtechnology,1999,27(3):251-255.)
|
| [5] | singhid,kothiyalv,ramaswamyv.characteristicchangesofasphaltenesduringvisbreakingofnorthgujaratshortresidue[j].fuel,1990,69(3):289-292.
|
| [6] | singhid,kothiyalv,kapoormp.structuralchangesduringvisbreakingoflightarabianmixshortresidue:comparisonoffeedandproductasphaltenes[j].fuel,1993,72(6):751-754.
|
| [7] | ancheytaj,centenog,trejof.changesinasphaltenepropertiesduringhydrotreatingofheavycrudes[j].energyfuels,2003,17(5):1233-1238.
|
| [8] | ancheytaj,centenog,trejof.asphaltenecharacterizationasfunctionoftimeon-streamduringhydroprocessingofmayacrude[j].cataltoday,2005,109(1/4):162-166.
|
| [9] | 孙昱东,杨朝合,谷志杰.反应温度对加氢残渣油四组分含量和结构的影响[j].燃料化学学报,2013,41(3):309-313.(sunyu-dong,yangchao-he,guzhi-jie.influenceofreactiontemperatureonthecontentandstructureoffourfractionsinresiduehydrotreating[j].journaloffuelchemistryandtechnology,2013,41(3):309-313.)
|
| [10] | 邓文安,阙国和.胜利减压渣油胶质热反应生焦特性的研究[j].石油学报(石油加工),1997,13(1):1-6.(dengwen-an,queguo-he.astudyoncharacteristicsofcokeformationaboutthermalreactionofresins[j].actapetroleisinica(petroleumprocessingsection),1997,13(1):1-6.)
|
| [11] | brownj,ladnerw.astudyofthehydrogendistributionincoal-likematerialsbyhigh-resolutionnuclearmagneticresonancespectroscopyii-acomparisonwithinfra-redmeasurementandtheconversiontocarbonstructure[j].fuel,1960,39(1):87-96.
|
| [12] | 梁文杰,阙国和,陈月珠.我国原油减压渣油的化学组成与结构-ii.减压渣油及其各组分的平均结构[j].石油学报(石油加工),1991,7(4):1-11.(liangwen-jie,queguo-he,chenyue-zhu.chemicalcompositionandstructureofvacuumresiduesofchinesecrudesii.averagestructureofvacuumresiduesandtheirfractions[j].actapetroleisinica(petroleumprocessingsection),1991,7(4):1-11.)
|
| [13] | 粱文杰.重质油化学[m].东营:石油大学出版社,2000.(liangwen-jie.heavyoilchemistry[m].dongying:chinauniversityofpetroleumpress,2000.)
|
| [14] | savagepe,kleinmt,kukessg.asphaltenereactionpathways:1.thermolysis[j].indengchemprocdesdev,1985,24(4):1169-1174.
|
| [15] | 张会成,邓文安.胜利渣油在供氢剂和溶剂下的热裂化特性研究[j].石油学报(石油加工),1997,13(2):17-22.(zhanghui-cheng,dengwen-an.studyonthermalreactioncharacteristicsofshenglivacuumresiduewithhydrogendonorandsolvent[j].actapetroleisinica(petroleumprocessingsection),1997,13(2):17-22.)
|
| [16] | hausera,bahzadd,stanislausa.thermogravimetricanalysisstudiesonthethermalstabilityofasphaltenes:pyrolysisbehaviorofheavyoilasphaltenes[j].energyfuels,2007,22(1):449-454.
|
| [17] | rahmanis,mccaffreyw,graymr.kineticsofsolventinteractionswithasphaltenesduringcokeformation[j].energyfuels,2001,16(1):148-154.
|
| [18] | 李生华,刘晨光.渣油热反应体系中第二液相与焦的关系[j].燃料化学学报,1998,26(1):1-6.(lisheng-hua,liuchen-guang.reactionsbetweensecondliquidphasesandcokeinthermalreactionsystemsofvacuumresidua[j].journaloffuelchemistryandtechnology,1998,26(1):1-6.)
|
| [19] | michaelg,al-sirim,khanzh.differencesinaveragechemicalstructuresofasphaltenefractionsseparatedfromfeedandproductoilsofamildthermalprocessingreaction[j].energyfuels,2005,19(4):1598-1605.
|
| [20] | 王宗贤,阙国和,粱文杰.渣油中硫和硫类型分布对热转化产物中硫分布的影响[j].石油学报(石油加工),1999,15(1):17-20.(wangzong-xian,queguo-he,liangwen-jie.effectofsulfurformsinvacuumresiduesonthedistributionofsulfurinthermalconversionproducts[j].actapetroleisinica(petroleumprocessingsection),1999,15(1):17-20.)
|
| [21] | 崔文龙,刘东,邓文安.渣油热反应过程中类型硫的转化规律[j].石油学报(石油加工),2012,28(2):248-253.(cuiwen-long,liudong,dengwen-an.conversionregularityofsulfurtypesduringresiduethermalreaction[j].actapetroleisinica(petroleumprocessingsection),2012,28(2):248-253.)
|
| [22] | curtiscw,guinja,halema.contributionoftransferablehydrogentocoalconversion[j].fuel,1985,64(4):461-469.
|
| [23] | 刘晨光,阙国和,陈月珠.用液相色谱及~1h-nmr波谱法评价减压渣油[j].石油学报(石油加工),1987,3(3):90-98.(liuchen-guang,queguo-he,chenyue-zhu.characterizationofvacuumresiduesbyliquidchromatographytechniqueand1h-nmrspectroscopy[j].actapetroleisinica(petroleumprocessingsection),1987,3(3):90-98.)
|
Full-Text
|
|
Contact Us
service@oalib.com QQ:3279437679 
WhatsApp +8615387084133
|
|
