OALib Journal期刊
ISSN: 2333-9721
费用:99美元
|
|
|
光辐照驱动水-碳低温催化制氢实验研究
, PP. 1102-1107
Keywords: 聚光太阳能,水-碳催化气化,催化机理,能量转化效率,氢
Abstract:
?在氙灯模拟的太阳光聚光反应系统上,以k2co3作为催化剂进行了700~720℃条件下的水-碳低温催化制氢实验。结果表明,催化作用下的产氢速率是未添加催化剂时的10倍,催化剂添加量在10%~20%时反应产氢率没有本质的区别。具体分析了k2co3催化水-碳制氢反应的氧转移机理,并用该机理对反应产物中出现的氢、氧不平衡现象做出了解释。实验中,光能转换化为化学能的效率达到13.12%,优于光伏法制氢效率10.85%。最后对进一步提高能量转换效率提出了可参考的思路。
References
[1] | steinfelda,weimeraw.thermochemicalproductionoffuelswithconcentratedsolarenergy[j].optexpress,2010,18(s1):a100-a111.
|
[2] | romeromanuel,steinfeldaldo.concentratingsolarthermalpowerandthermochemicalfuels[j].energyenvironsci,2012,5(11):9234-9245.
|
[3] | smestadgp,steinfelda.review:photochemicalandthermochemicalproductionofsolarfuelsfromh2oandco2usingmetaloxidecatalysts[j].indengchemres,2012,51(37):11828-11840.
|
[4] | xiaol,wusy,liyr.advancesinsolarhydrogenproductionviatwo-stepwater-splittingthermochemicalcyclesbasedonmetalredoxreactions[j].renewableenergy,2012,41:1-12.
|
[5] | kodamat,kiyamaa.solarmethanereformingusinganewtypeofcatalytically-activatedmetallicfoamabsorber[j].jsolenergyeng,2004,126(2):808-811.
|
[6] | bermana,karnrk,epsteinm.anewcatalystsystemforhigh-temperaturesolarreformingofmethane[j].energyfuels,2006,20(2):455-462.
|
[7] | wangj,sakanishik,saitoi.high-yieldhydrogenproductionbysteamgasificationofhypercoal(ash-freecoalextract)withpotassiumcarbonate:comparisonwithrawcoal[j].energyfuels,2005,19(5):2114-2120.
|
[8] | 金会心,王华.聚光太阳能加热昭通褐煤的气化试验研究[j].燃料化学学报,2001,29(6):548-551.(jinhui-xin,wanghua.gasificationofzhaotongligniteheatedbyconcentratedsolarenergy[j].journaloffuelchemistryandtechnology,2001,29(6):548-551.)
|
[9] | wangj,jiangmq,yaoyh,zhangym,caojq.steamgasificationofcoalcharcatalyzedbyk2co3forenhancedproductionofhydrogenwithoutformationofmethane[j].fuel,2009,88(9):1572-1579.
|
[10] | 王宝辉,吴红军,刘淑芝,盖翠萍.太阳能分解水制氢技术研究进展[j].化工进展,2006,25(7):733-738.(wangbao-hui,wuhong-jun,liushu-zhi,gaicui-ping.advanceonresearchofhydrogenproductionbysolarwatersplitting[j].chemicalindustryandengineeringprogress,2006,25(7):733-738.)
|
[11] | tributschh.photovoltaichydrogengeneration[j].intjhydrogenenergy,2008,33(21):5911-5930.
|
[12] | stamatioua,loutzenhiserpg,steinfelda.solarsyngasproductionviah2o/co2-splittingthermochemicalcycleswithzn/znoandfeo/fe3o4redoxreactions[j].chemmater,2010,22(3):851-859.
|
[13] | 祝星,王华,魏永刚,李孔斋,晏冬霞.金属氧化物两步法化学循环分解水制氢化学进[j].2010,22(5):1010-1020.(zhuxing,wanghua,weiyong-gang,likong-zhai,yandong-xia.hydrogenproductionbytwo-stepwater-splittingthermochemicalcyclebasedonmetaloxideredoxsystem[j].progressinchemistry,2010,22(5):1010-1020.)
|
[14] | nobuyukig,tetsurom,nobuyukik,tatsuyak.thermochemicaltwo-stepwatersplittingbyinternallycirculatingfluidizedbedofnife2o4particles:successivereactionofthermal-reductionandwater-decompositionsteps[j].intjhydrogenenergy,2011,36(8):4757-4767.
|
[15] | wornera,tammer.co2reformingofmethaneinasolardrivenvolumetricreceiver-reactor[j].cataltoday,1998,46(2):165-174.
|
[16] | buckr,muirjf,hoganre.carbondioxidereformingofmethaneinasolarvolumetricreceiver/reactor:thecaesarproject[j].solenergymater,1991,24(1):449-463.
|
[17] | muirj,hoganr,skocypecr,buckr.solarreformingofmethaneinadirectabsorptioncatalyticreactoronaparabolicdish:i-testandanalysis[j].solarenergy,1994,52(6):467-477.
|
[18] | moulijnja,kapteijnf.towardsaunifiedtheoryofreactionsofcarbonwithoxygen-containingmolecules[j].carbon,1995,33(8):1155-1165.
|
[19] | 孙雪莲,王黎,张占涛.煤气化复合催化剂研究及机理探讨[j].煤炭转化,2006,29(1):15-18.(sunxue-lian,wangli,zhangzhan-tao.studyoncompoundcatalystforgasificationanditsmechanism[j].coalconversion,2006,29(1):15-18.)
|
[20] | 郝西维,王黎,吴嘉州.煤温和气化技术研究进展[j].煤炭转化,2008,31(2):83-89.(haoxi-wei,wangli,wujia-zhou.progressofresearchoncoalmildgasification[j].coalconversion,2008,31(2):83-89.)
|
[21] | 徐秀峰,顾永达,陈诵英.煤焦气化反应的影响因素和反应机理的研究进展[j].煤炭转化,1996,19(2):48-53.(xuxiu-feng,guyong-da,chensong-ying.thestudyofinfluentialfactorstochargasificationreactionandmechanism[j].coalconversion,1996,19(2):48-53.)
|
Full-Text
|
|
Contact Us
service@oalib.com QQ:3279437679 
WhatsApp +8615387084133
|
|