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OALib Journal期刊
ISSN: 2333-9721
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分子筛硅铝比及晶粒粒径对cu-zno-al2o3/hzsm-5催化剂直接合成二甲醚反应性能的影响
, PP. 235-240
Keywords: hzsm-5分子筛,硅铝比,晶粒大小,二甲醚,双功能催化剂,甲醇脱水
Abstract:
？采用水热晶化法合成了硅铝比(sio2/al2o3)为60、120、200和晶粒粒径分别为1.00和0.25μm的hzsm-5分子筛,并以其为甲醇脱水活性组分与铜基甲醇合成活性组分(cu-zno-al2o3)组成双功能催化剂(cu-zno-al2o3/hzsm-5),在连续流动加压固定床反应器上考察了cu-zno-al2o3/hzsm-5对合成气直接制二甲醚反应的催化性能。结果表明,随着分子筛硅铝比的提高,二氧化碳副产物的生成量逐渐减少,从而使目的产物二甲醚的选择性逐渐增大。与常规分子筛相比,小晶粒分子筛的反应活性接近,但二氧化碳和烃类副产物的选择性较低。
| [1] | 秦冉冉,常杰,叶跃元,范娟.一步法制二甲醚双功能催化剂研究进展[j].可再生能源,2009,27(6):96-101.(qinran-ran,changjie,yeyue-yuan,fanjuan.bifunctionalcatalystsfordirectsynthesisofdimethyletherfromsyngas[j].renewableenergyresources,2009,27(6):96-101.)
|
| [2] | 别良伟,王华.合成气一步法制二甲醚催化剂研究进展[j].工业催化,2009,17(2):34-39.(bieliang-wei,wanghua.advancesindevelopmentsofthecatalystsforone-stepsynthesisofdimethyletherfromsyngas[j].industrialcatalysis,2009,17(2):34-39.)
|
| [3] | sofianosac,scurrellms.conversionofsynthesisgastodimethyletheroverbifunctionalcatalyticsystems[j].indengchemres,1991,30(11):2372-2378.
|
| [4] | 陈建刚,牛玉琴.hzsm-5分子筛与铜基的复合催化剂上合成气制二甲醚[j].天然气化工,1997,22(6):6-10.(chenjian-gang,niuyu-qin.ahybridcatalystfordmesynthesisfromsyngaswithhzsm-5asdehydrationcatalyst[j].naturalgaschemicalindustry,1997,22(6):6-10.)
|
| [5] | takeguchit,yanagisawak,inuit,inouem.effectofthepropertyofsolidaciduponsyngas-to-dimethyletherconversiononthehybridcatalystscomposedofcu-zn-gaandsolidacids[j].applcatala,2000,192(2):201-209.
|
| [6] | jooos,jungkd,hansh.modificationofhzsm-5andγ-aluminawithformaldehydeanditsapplicationtothesynthesisofdimethyletherfromsyn-gas[j].bullkoreanchemsoc,2002,23(8):1103-1105.
|
| [7] | 鲁皓,常杰,付严,王铁军.hzsm-5型分子筛硅铝比对一步法合成二甲醚的影响[j].燃料化学学报,2005,33(3):324-328.(luhao,changjie,fuyan,wangtie-jun.studyoftheeffectsofsi/alratioofhzsm-5onthedirectsynthesisofdme[j].journaloffuelchemistryandtechnology,2005,33(3):324-328.)
|
| [8] | 许庆利,李庭琛,张素平,任铮伟,颜涌捷.分子筛改性对一步法合成二甲醚的影响[j].燃料化学学报,2008,36(1):74-78.(xuqing-li,liting-chen,zhangsu-ping,renzheng-wei,yanyong-jie.effectofthemodifiedzeoliteonone-stepdimethylethersynthesis[j].journaloffuelchemistryandtechnology,2008,36(1):74-78.)
|
| [9] | xiaj,maod,zhangb,chenq,tangy.one-stepsynthesisofdimethyletherfromsyngaswithfe-modifiedzeolitezsm-5asdehydrationcatalyst[j].catallett,2004,98(4):235-240.
|
| [10] | kimjh,parkmj,kimsj,jooos,jungkd.dmesynthesisfromsynthesisgasontheadmixedcatalystsofcu/zno/al2o3andzsm-5[j].applcatala,2004,264(1):37-41.
|
| [11] | 刘志坚,廖建军,谭经品,李大东.甲醇脱水生成二甲醚的沸石催化剂[j].石油化工,1999,28(4):236-240.(liuzhi-jian,liaojian-jun,tanjing-pin,lida-dong.studyonthezeolitecatalystsfordimethylethersynthesisfrommethanol[j].petrochemicaltechnology,1999,28(4):236-240.)
|
| [12] | kangs-h,baejw,junk-w,potdarhs.dimethyleethersynthesisfromsyngasoverthecompositecatalystsofcu-zno-al2o3/zr-modifiedzeolites[j].catalcommun,2008,9(10):2035-2039.
|
| [13] | 毛东森,郭强胜,卢冠忠.分子筛晶粒大小及磷改性对zsm-5催化甲醇转化制丙烯的影响[j].石油学报(石油加工),2009,25(4):503-508.(maodong-sen,guoqian-sheng,luguan-zhong.effectsofcrystalsizeandphosphorusmodificationoncatalyticconversionofmethanoltopropyleneoverzsm-5zeolite[j].actapetroleisinica(petroleumprocessingsection),2009,25(4):503-508.)
|
| [14] | 滕加伟,赵国良,谢在库,陈庆龄.zsm-5分子筛晶粒尺寸对c4烯烃催化裂解制丙烯的影响[j].催化学报,2004,25(8):602-606.(tengjia-wei,zhaoguo-liang,xiezai-ku,chenqing-ling.effectofzsm-5zeolitecrystalsizeonpropyleneproductionfromcatalyticcrackingofc4olefins[j].chinesejournalofcatalysis,2004,25(8):602-606.)
|
| [15] | shiralkarvp,joshipn,eapenmj,raobs.synthesisofzsm-5withvariablecrystallitesizeanditsinfluenceonphysicochemicalproperties[j].zeolites,1991,11(1/3):511-516.
|
| [16] | singhm,kambler,viswanadhamn.effectofcrystalsizeonphysico-chemicalpropertiesofzsm-5[j].catallett,2008,120(3/4):288-293.
|
| [17] | erenaj,garonar,arandesjm,aguayoat,bilbaoj.effectofoperatingconditionsonthesynthesisofdimethyletheroveracuo-zno-al2o3/nahzsm-5bifunctionalcatalyst[j].cataltoday,2005,107-108(1/4):467-473.
|
| [18] | wangl,qiy,weiy,fangd,mengs,liuz.researchontheacidityofthedouble-functioncatalystfordmesynthesisfromsyngas[j].catallett,2006,106(1/2):61-66.
|
| [19] | maod,xiaj,zhangb,lug.highlyefficientsynthesisofdimethyletherfromsyngasovertheadmixedcatalystofcuo-zno-al2o3andantimonyoxidemodifiedhzsm-5zeolite[j].energyconversmanage,2010,51(6):1134-1139.
|
| [20] | 何凤仙,唐秀娟,费金华,郑小明.金属组分负载量对cu-mn-zn/y直接合成二甲醚催化剂的影响[j].燃料化学学报,2006,34(2):191-194.(hefeng-xian,tangxiu-juan,feijin-hua,zhengxiao-ming.effectofthecontentofmetalliccomponentoncu-mn-zn/ycatalystsfordirectsynthesisofdme[j].journaloffuelchemistryandtechnology,2006,34(2):191-194.)
|
| [21] | 于翔,王军华,张立伟,侯昭胤,费金华,郑小明.甲醇及合成气制二甲醚中不同粒径的hy分子筛及复合cu-mn-zn/hy催化剂[j].催化学报,2010,31(5):591-596.(yuxiang,whangjun-hua,zhangli-wei,houzhao-yin,feijin-hua,zhengxiao-ming.dimethylethersynthesisfrommethanolandsyngasoverdifferentsizedhyzeoliteandcu-mn-zn/hybifunctionalcatalyst[j].chinesejournalofcatalysis,2010,31(5):591-596.)
|
| [22] | yooks,kimjh,parkmj,kimsj,jooos,jungkd.influenceofsolidacidcatalystondmeproductiondirectlyfromsynthesisgasovertheadmixedcatalystofcu/zno/al2o3andvarioussapocatalysts[j].applcatala,2007,330(1):57-62.
|
| [23] | maod,xiaj,chenq,lug.highlyeffectiveconversionofsyngastodimethyletheroverthehybridcatalystscontaininghighsilicahmcm-22zeolites[j].catalcommun,2009,10(5):620-624.
|
| [24] | baejw,kangs-h,leey-j,junk-w.synthesisofdmefromsyngasonthebifunctionalcu-zno-al2o3/zr-modifiedferrierite:effectofzrcontent[j].applcatalb,2009,90(3/4):426-435.
|
| [25] | 许庆利,李庭琛,张素平,任铮伟,颜涌捷.固体酸脱水剂表面酸性对一步法合成二甲醚的影响[j].过程工程学报,2007,7(5):905-909.(xuqing-li,liting-chen,zhangsu-ping,renzheng-wei,yanyong-jie.effectofsolidacidasdchydrantonone-stepdmesynthesis[j].thechinesetournalofprocessengineering,2007,7(5):905-909.)
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