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OALib Journal期刊
ISSN: 2333-9721
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fe2o3/al2o3氧载体用于甲烷化学链燃烧：负载量与制备方法的影响
, PP. 1384-1392
Keywords: 甲烷化学链燃烧,fe2o3/al2o3氧载体,负载量,制备方法
Abstract:
？以不同方法制备了系列fe2o3/al2o3氧载体,采用xrd、h2-tpr、ch4-tpr、o2-tpd和bet等分析技术对氧载体进行了表征。研究了不同fe2o3负载量氧载体的甲烷化学链燃烧性能,考察了不同制备方法对fe2o3/al2o3氧载体结构、反应性和产物选择性的影响。结果表明,fe2o3负载量对氧载体活性及产物中co2选择性的影响较大,负载量较低时氧载体活性较低且引起甲烷部分氧化产物co含量增加。制备方法亦对氧载体与甲烷的反应活性有所影响,整体上共沉淀法制备的质量分数60％fe2o3/al2o3氧载体具有较高的氧化活性和化学链循环稳定性。其在反应温度850℃、反应时间15min、30次循环后甲烷转化率及产物中co2选择性均未见明显降低。
| [1] | 沈来宏,肖军,肖睿,张辉.基于caso4载氧体的煤化学链燃烧分离co2研究[j].中国电机工程学报,2007,27(2):69-74.(shenlai-hong,xiaojun,xiaorui,zhanghui.chemicalloopingcombustionofcoalininterconnectedfluidizedbedsofcaso4oxygencarrier[j].proceedingsofthecsee,2007,27(2):69-74.)
|
| [2] | 郑瑛,王保文,宋侃,郑楚光.化学链燃烧技术中新型氧载体caso4的特性研究[j].工程热物理学报,2006,27(3):531-533.(zhengying,wangbao-wen,songkan,zhengchu-guang.theperformanceresearchonnewoxygencarriercaso4usedinchemical-loopingcombustion[j].journalofengineeringthermophysics,2006,27(3):531-533.)
|
| [3] | hossainm,delasah.chemical-loopingcombustion(clc)forinherentco2separations-areview[j].chemiengineersci,2008,63:4433-4451.
|
| [4] | adanezj,dediegoluisf,garcia-labianof,gayanp,abada,palaciosjm.selectionofoxygencarriersforchemical-loopingcombustion[j].energyfuels,2004,18(2):371-377.
|
| [5] | jinhg,hongh,hant.progressofenergysystemwithchemical-loopingcombustion[j].chinesesciencebulletin,2008,54(6):906-919.
|
| [6] | 金红光,王宝群.化学能梯级利用机理探讨[j].工程热物理学报,2004,25(2):181-184.(jinhong-guang,wangbao-qun.principleofcascadeutilizationofchemicalenergy[j].journalofengineeringthermophysics,2004,25(2):181-184.)
|
| [7] | thomasdc,bensons.carbondioxidecaptureforstorageindeepgeologicformations:resultsfromtheco2captureproject[m].elsevier,2005.
|
| [8] | kerrhr.captureandseparationtechnologiesgapsandpriorityresearchneeds[j].carbondioxidecaptureforstorageindeepgeologicformations-resultsfromtheco2captureproject,2005,1.
|
| [9] | 刘黎明,赵海波,郑楚光.化学链燃烧方式中氧载体的研究进展[j].煤炭转化,2006,29(3):83-93.(liuli-ming,zhaohai-bo,zhengchu-guang.advancesonoxygencarriersofchemical-loopingcombustion[j].coalconversion,2006,29(3):83-93.)
|
| [10] | adanezj,garcia-labianof,dediegoluisf.nickel-copperoxygencarrierstoreachzerocoandh2emissionsinchemical-loopingcombustion[j].indengchemres,2006,45(8):2617-2625.
|
| [11] | 高正平,沈来宏,肖军,吴家桦.基于fe2o3载氧体的煤化学链燃烧试验[j].中国工程热物理学报,2009,30(7):1249-1252.(gaozheng-ping,shenlai-hong,xiaojun,wujia-hua.multicyclereductionofcoalasfuelforchemical-loopingcombustionwithfe-basedoxygencarrier[j].journalofengineeringthermophysics,2009,30(7):1249-1252.)
|
| [12] | 宋涛,沈来宏,肖军,高正平,顾海明,张思文.铁矿石载氧体化学链燃烧高温还原表征[j].燃料化学学报,2011,39(8):567-574.(songtao,shenlai-hong,xiaojun,gaozheng-ping,guhai-ming,zhangsi-wen.characterizationofhematiteoxygencarrierinchemical-loopingcombustionathighreductiontemperature[j].journaloffuelchemistryandtechnology,2011,39(8):567-574.)
|
| [13] | sonsr,goks,kimsd.thermogravimetricanalysisofcopperoxideforchemical-loopinghydrogengeneration[j].indengchemres,2009,48(1):380-387.
|
| [14] | mattissont,leionh,lyngfelta.chemical-loopingwithoxygenuncouplingusingcuo/zro2withpetroleumcoke[j].fuel,2009,88(4):683-690.
|
| [15] | 梅道锋,赵海波,马兆军,郑楚光.fe2o3/al2o3氧载体制备方法的研究[j].燃料化学学报,2012,40(7):795-802.(meidao-feng,zhaohai-bo,mazhao-jun,zhengchu-guang.preparationmethodstudyonfe2o3/al2o3oxygencarrier[j].journaloffuelchemistryandtechnology,2012,40(7):795-802.)
|
| [16] | wangb,yanr,leed,zhengy,zhaoh,zhengc.characterizationandevaluationoffe2o3/al2o3oxygencarrierpreparedbysol-gelcombustionsynthesis[j].janalapplpyrolysis,2011,91(1):105-113.
|
| [17] | zhangl,wangx,milletj,matterp,ozkanu.investigationofhighlyactivefe-al-cucatalystsforwater-gasshiftreaction[j].applcatala:gen,2008,351(1):1-8.
|
| [18] | magnaccag,cerratog,morterrac,signorettom,sommaf,pinnaf.structuralandsurfacecharacterizationofpureandsulfatedironoxides[j].chemmater,2003,15:675-87.
|
| [19] | kockajhm,fortuinhm,geusjw.thereductionbehaviorofsupportedironcatalystsinhydrogenorcarbonmonoxideatmospheres[j].jcatal,1985,96(1):261-275.
|
| [20] | barosaal,herguidoj,santamariaj.methanecombustionoverunsupportedironoxidecatalysts[j].cataltoday,2001,64:43-50.
|
| [21] | daixp,lirj,yucc,haozp.unsteady-statedirectpartialoxidationofmethanetosynthesisgasinafixed-bedreactorusingafeo(3)(a=la,nd,eu)perovskite-typeoxidesasoxygenstorage[j].jphyschemb,2006,110:22525-22531.
|
| [22] | gemmim,merlinim,cornarou,ghislettid,artiolig.insitusimultaneoussynchrotronpowderdiffractionandmassspectrometrystudyofmethaneanaerobiccombustiononiron-oxide-basedoxygencarrier[j].japplcryst,2005,38:353-360.
|
| [23] | turnockac,eugsterhp.fe-aloxides:phaserelationshipsbelow1000℃[j].petrology,1962,3(3):533-565.
|
| [24] | leionh,mattisssont,lyngfelta.useoforesandindustrialproductsasoxygencarriersinchemical-loopingcombustion[j].energyfuels,2009,23(4):2307-15.
|
| [25] | kidambipr,cleetonjpe,scottsa,dennisjs,bohncd.interactionofironoxidewithaluminainacompositeoxygencarrierduringtheproductionofhydrogenbychemicallooping[j].energyfuels,2012,26(1):603-617.
|
| [26] | adanezj,abada,garcia-labianof,gayanp,dediegolf.progressinchemical-loopingcombustionandreformingtechnologies[j].progenergycombustsci,2012,38(2):215-282
|
| [27] | 刘黎明.煤基化学链燃烧技术的氧载体研究[d].华中科技大学,2007.(liuli-ming.studyonoxygencarriersforchemicalloopingcombustionofcoal[d].huazhonguniversityofscienceandtechnology,2007.)
|
| [28] | 高正平,沈来宏,肖军,郑敏,吴家桦.煤化学链燃烧fe2o3载氧体的反应性研究[j].燃料化学学报,2009,37(5):513-520.(gaozheng-ping,shenlai-hong,xiaojun,zhengmin,wujia-hua.analysisofreactivityoffe-basedoxygencarrierwithcoalduringchemical-loopingcombustion[j].journaloffuelchemistryandtechnology,2009,37(5):513-520.)
|
| [29] | lyngfelta,lecknerb.technologyforco2separation[c]//minisymposiumoncarbondioxidecaptureandstorage,schoolofenvironmentalsciences,cthandgu,ed.lygnfelt,a,azarc,1999:25-35.
|
| [30] | richterhj,knochek.reversibilityofcombustionprocess[c]//efficiencyandcosting-secondlawanalysisofprocesses(acssymposiumseries).washingtondc:americanchemicalsociety,1983:71-85.
|
| [31] | lyngfelta,kronbergerb,adanezj,morinjx,hurstp.thegraceproject.developmentofoxygencarrierparticlesforchemical-loopingcombustion.designandoperationofa10kwchemical-loopingcombustor[c]//7thinternationalconferenceongreenhousegascontroltechnologies,vancouver,canada,2004.
|
| [32] | chop,mattissont,lyngfelta.comparisonofiron-,nickel-andmanganese-basedoxygencarriersforchemical-loopingcombustion[j].fuel,2004,83(9):1215-1225.
|
| [33] | dediegoluisf,garcia-labianof,adanezj.developmentofcu-basedoxygencarriersforchemical-loopingcombustion[j].fuel,2004,83(13):1749-1757.
|
| [34] | mattissont,johanssonm,lyngfelta.multicyclereductionandoxidationofdifferenttypesofironparticlesapplicationtochemical-loopingcombustion[j].energyfuels,2004,18(3):628-637.
|
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