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酸碱改性hzsm-5分子筛上甲醇制取均四甲苯的研究

, PP. 102-109

Keywords: hzsm-5,甲醇,均四甲苯,碱处理,酸处理

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Abstract:

?对hzsm-5分子筛进行"酸碱两步改性",制备得到了h(0.2)-na-zsm-5、h(0.5)-na-zsm-5、h(0.2)-k-zsm-5和h(0.5)-k-zsm-5四种催化剂。通过xrd、nh3-tpd、icp、ft-ir与py-ir方法对催化剂进行表征,并在连续流动固定床反应装置上对催化剂进行评价。实验结果表明,h(0.2)-k-zsm-5催化剂由于其孔径变大、弱的b酸量增多,从而提高了均四甲苯的选择性。

References

[1]  maejimat.processforhighlyselectiveproductionofpolyalkylbenzenes:ep,101651[p].1984-02-29.
[2]  niwas.partialnucleus-hydrogenationofaromatichydrocarbon:jp,59-155328[p].1984-09-04.
[3]  付中林.浅谈重芳烃的利用[j].福建化工,2000,4(5):8-9.(fuzhong-lin.discussionwithutilizationofheavyaromatics[j].fujianchemicalengineering,2000,4(5):8-9.)
[4]  garwoodwe,leew,schoennagelhj.hydrotreatingofbottomsfractionsresultingfromconversionofmethanoltogasolineinordertodecreasedureneandproducedistillate:us,4304951[p].1981-12-08.
[5]  dwyerfg,hussajr.treatmentofeffluentresultingfromconversionofmethanoltogasolineinordertodeceasedureneandproducedistillate:us,4347397[p].1982-08-31.
[6]  changcd,silvestriaj.theconversionofmethanolandothero-compoundstohydrocarbonsoverzeolitecatalysts[j].jcatal,1977,47(2):249-259.
[7]  胡津仙,王俊杰,任杰,李永旺,孙予罕.用于甲醇合成均四甲苯的分子筛催化剂制备和应用:中国,1421271a[p].2003-06-04.(hujin-xian,wangjun-jie,renjie,liyong-wang,sunyu-han.preparationandapplicationofmolecularsievezeolitesformethanolconvertingtodurene:cn,1421271a[p].2003-06-04.)
[8]  groenjc,moulijnja,perez-ramirezj.alkalineposttreatmentofmfizeolites.fromacceleratedscreeningtoscale-up[j].indengchemres,2007,46(12):4193-4201.
[9]  groenjc,pefferlaa,moulijnja,perez-ramirezj.mesoporositydevelopmentinzsm-5zeoliteuponoptimizeddesilicationconditionsinalkalinemedium[j].colloidsurfa,2004,241(1/3):53-58.
[10]  luisap,francescab,pablob,mortenb,adrianoz,silviab.conversionofmethanoltohydrocarbons:spectroscopiccharacterizationofcarbonaceousspeciesformedoverh-zsm-5[j].jphyschemc,2008,112(26):9710-9716.
[11]  onoy,morit.surfacereactivityofzeolitestypeh-yandna-ywithmethanol[j].jchemsoc,faradaytrans,1977,73:1153-1168.
[12]  殷丽娜,胡永玲,韩大维.均四甲苯的制备方法及应用研究[j].化学与粘合,2009,31(6):64-68.(yinli-na,huyong-ling,handa-wei.preparationandapplicationofdurene[j].chemistryandadhesion,2009,31(6):64-68.)
[13]  赵开鹏,韩松.重整c10芳烃的综合利用[j].石油化工,2000,29(4):298-302.(zhaokai-peng,hansong.comprehensiveutilizationofc10aromaticsfromcatalyticreformunit[j].petrochemicaltechnology,2000,29(4):298-302.)
[14]  李慧民.偏四甲苯液相异构化制均四甲苯[j].化学与粘合,1992,(2):72-76.(lihui-min.synthesisof1,2,3,5-tetramethylbenzenebyliquidphaseisomerizationofdurene[j].chemistryandadhesion,1992,(2):72-76.)
[15]  贾定先,李栋藩,张盈珍.含锆层柱蒙脱石对1,2,4-三甲苯歧化反应的催化作用[j].催化学报,1998,19(1):58-62.(jiading-xian,lidong-fan,zhangying-zhen.disproportionationof1,2,4–trimethylbenzeneoverzrcontainingpillaredmontmorillonite[j].chinesejournalofcatalysis,1998,19(1):58-62.)
[16]  tennakoon,tilakb,jonesw.structuralaspectsofmetal-oxide-pillaredsheetsilicates:aninvestigationbymagic-angle-spinningnuclearmagneticresonance,fourier-transforminfraredspectroscopyandpowderx-raydiffractometry[j].jchemsoc,faradaytransi,1986,82(10):3081-3095.
[17]  karlb.verfahrenzurisomerisierungvontetramethylbenzolen:dl(east),137703[p].1979-09-19.
[18]  karlb.verfahrenzurisomerisierungvontetramethylbenzolen:dl(east),137704[p].1979-09-19.
[19]  groenjc,jansenjc,moulijnja,perez-ramirezj.optimalaluminum-assistedmesoporositydevelopmentinmfizeolitesbydesilication[j].jphyschemb,2004,108(45):13062-13065.
[20]  groenjc,bacht,zieseu,paulaime-vandonkam,jongkp,moulijnja,perez-ramirezj.creationofhollowzeolitearchitecturesbycontrolleddesilicationofal-zonedzsm-5crystals[j].jamchemsoc,2005,127(31):10792-10793.
[21]  groenjc,moulijnja,perez-ramirezj.decouplingmesoporosityformationandaciditymodificationinzsm-5zeolitesbysequentialdesilication-dealumination[j].microporousmesoporousmater,2005,87(2):153-161.
[22]  groenjc,pefferlaa,moulijnja,perez-ramirezj.mechanismofhierarchicalporositydevelopmentinmfizeolitesbydesilication:theroleofaluminiumasapore-directingagent[j].chemeurj,2005,11(17):4983-4994.
[23]  李钢,郭新闻,王祥生,李光岩,赵琦,包信和,韩秀文,林励吾.tpabr-2正丁胺体系中ts-1的合成与表征[j].大连理工大学学报,1998,38(3):363-367.(ligang,guoxin-wen,wangxiang-sheng,liguang-yan,zhaoqi,baoxin-he,hanxiu-wen,linli-wu.synthesisandcharacterizationofts-1inpresenceoftpabr-2andbutylamine[j].journalofdalianuniversityoftechnology,1998,38(3):363-367.)
[24]  niym,sunam,wuxl,haigl,hujl,lit,ligx.preparationofhierarchicalmesoporouszn/hzsm-5catalystanditsapplicationinmtgreaction[j].jnatgaschem,2011,20(3):237–242.
[25]  辛勤,梁长海.固体催化剂的研究方法:第八章红外光谱法(中)[j].石油化工,2001,30(2):157-167.(xinqin,liangchang-hai.researchmethodsofsolidcatalyst:chapter8.infraredspectroscopy(parttwo)[j].petrochemicaltechnology,2001,30(2):157-167.)
[26]  mortenb,finnj,martinsh,unnio,karl-petterl,stians.methanoltogasolineoverzeoliteh-zsm-5:improvedcatalystperformancebytreatmentwithnaoh[j].applcatala,2008,345(1):43-50.
[27]  michaels.methanol-to-hydrocarbons:catalyticmaterialsandtheirbehavior[j].microporousmesoporousmater,1999,29(1/2):3-48.
[28]  sayedmb,kyddra,cooneyrp.afourier-transforminfraredspectralstudyofh-zsm-5surfacesitesandreactivitysequencesinmethanolconversion[j].jcatal,1984,88(1):137-149.

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