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OALib Journal期刊
ISSN: 2333-9721
费用：99美元
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生物油模型化合物催化裂化制备芳香烃的实验研究
, PP. 183-188
Keywords: 模型化合物,催化裂化,生物油,hzsm-5,芳香烃
Abstract:
？通过hzsm-5分子筛催化剂对生物油典型模型化合物(乙酸、愈创木酚、正庚烷和环己烷等)在550℃进行了催化裂化反应,研究模型化合物催化裂化特性和反应机理以及催化剂性质。结果表明,正庚烷和环己烷裂化产物主要是芳香烃(53%和91%,均为积分面积分数),对于此类不含氧的模型化合物,催化裂化反应过程更容易进行;随着催化剂用量的增加,可以有效增加乙酸裂化产物中芳香烃含量(12%到90%,均为积分面积分数);愈创木酚结构比较复杂,hzsm-5催化剂主要脱除了甲氧基,催化剂用量的增加可以使芳香烃类稳定物质更容易形成。
| [1] | 熊万明,傅尧,来大明,郭庆祥.酸性离子交换树脂催化酯化改质生物油的研究[j].高等学校化学学报,2009,30(9):1754-1758.(xiongwan-ming,fuyao,laida-ming,guoqing-xiang.upgradingofbio-oilviaesterificationcatalystedwithacidicion-exchangeresin[j].chemicalresearchinchineseuniversities,2009,30(9):1754-1758.)
|
| [2] | kastnerjr,millerj,gellerdp,locklinj,keithlh,johnsont.catalyticesterificationoffattyacidsusingsolidacidcatalystsgeneratedfrombiocharandactivatedcarbon[j].cataltoday,2012,109(1):122-132.
|
| [3] | guyue-ling,yinqiang-qian,wangshu-rong,lixin-bao,guozuo-gang,luozhong-yang.experimentalstudyonthephysico-chemicalpropertiesofbio-oilanddieselemulsification[j].advancedmaterialsresearch,2012,433-440,94-99.
|
| [4] | gracai,lopesjm,ribeiromf,cerqueirahs,dealmeidambb.catalyticcrackinginthepresenceofguaiacol[j].applcatalb,2011,101(3/4):613-621.
|
| [5] | 刘熠斌,王洪刚,杨朝合,山红红.催化裂化汽油二次反应过程中反应热的变化[j].化工学报,2009,60(2):358-364.(liuyi-bin,wanghong-gang,yangchao-he,shanhong-hong.variationofreactionheatforsecondaryreactionoffccgasoline[j].journalofchemicalindustryandengineering(china),2009,60(2):358-364.)
|
| [6] | 王丽红,贾管臣,柏雪源,易维明,殷哲.生物质热解生物油的成分分析[j].太阳能学报,2009,30(8):1124-1128.(wangli-hong,jiaguan-chen,baixue-yuan,yiwei-ming,yinzhe.compositionalanalysisofbio-oilderivedfrompyrolysisofbiomass[j].actaenergiaesolarissinica,2009,30(8):1124-1128.)
|
| [7] | 常胜,赵增立,张伟,郑安庆,吴文强,李海滨.不同种类生物油化学组成结构的对比研究[j].燃料化学学报,2011,39(10):746-753.(changsheng,zhaozeng-li,zhangwei,zhengan-qing,wuwen-qiang,lihai-bin.comparisonofchemicalcompositionandstructureofdifferentkindsofbio-oils[j].journaloffuelchemistryandtechnology,2011,39(10):746-753.)
|
| [8] | 卢学栋,杨彩虹,窦秀云,李文彬,王定珠.直链烷烃在hzsm-5上裂解反应[j].石油学报(石油加工),1990,6(2):10-18.(luxue-dong,yangcai-hong,douxiu-yun,liwen-bin,wangding-zhu.catalyticcrackingofn-alkanesoverhzsm-5zeolite[j].actapetroleisinica(petroleumprocessingsection),1990,6(2):10-18.)
|
| [9] | 刘全杰,方向晨,贾立明,徐会青.正庚烷在hzsm-5沸石催化剂上芳构化反应研究[j].石油炼制与化工,2009,40(10):1-3.(liuquan-jie,fangxiang-chen,jiali-ming,xuhui-qing.studyonthen-heptanearomatizationreactionoverzsm-5zeolitecatalysts[j].petroleumprocessingandpetrochemicals,2009,40(10):1-3.)
|
| [10] | 王滨,高强,高建东,闫亮,王晓来,索继栓.高硅分子筛zsm-23的合成及表征[j].分子催化,2004,18(4):253-256.(wangbin,gaoqiang,gaojian-dong,yanliang,wangxiao-lai,suoji-shuan.synthesisandcharacterizationofzsm-23zeolitewithhighsilica[j].journalofmolecularcatalysis(china),2004,18(4):253-256.)
|
| [11] | luq,liw-z,zhux-f.overviewoffuelpropertiesofbiomassfastpyrolysisoils[j].energyconversmanage,2009,50(5):1376-1383.
|
| [12] | mohand,pittmancujr,steeleph.pyrolysisofwood/biomassforbio-oil:acriticalreview[j].energyfuels,2006,20(3):848-889.
|
| [13] | zhangq,changj,wangt-j,xuy.reviewofbiomasspyrolysisoilpropertiesandupgradingresearch[j].energyconversmanage,2007,48(1):87-92.
|
| [14] | 韩红睿,张瑞芹,徐兴敏,刘永刚,张长森.生物油-甲醇催化重整制氢的氢产率及碳转化率的研究[j].可再生能源,2012,30(8):69-73.(hanhong-rui,zhangrui-qin,xuxing-min,liuyong-gang,zhangchang-shen.studyinthehydrogenyieldandcarbonconversionrateofbio-oil-methanolcatalyticreforming[j].renewableenergyresourses,2012,30(8):69-73.)
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