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OALib Journal期刊
ISSN: 2333-9721
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煤催化气化中非均相反应动力学的研究
, PP. 290-296
Keywords: 催化气化,加压固定床,动力学,随机孔模型
Abstract:
？以神木煤焦为研究对象，在小型加压固定床上考察了不同气化剂（水蒸气、二氧化碳、氢气）、催化剂负载量、水蒸气分压、氢气分压和一氧化碳分压对碳转化率和气化反应速率的影响。结果表明，对于非均相的催化气化反应来说，反应速率顺序为c-h2o>c-co2>c-h2。h2和co不同程度地抑制煤焦水蒸气气化反应，co的抑制作用明显大于h2。在700℃，当添加5%的co，碳转化率降低约50%。基于langmuir-hinshelwood（l-h）方程，结合随机孔模型，同时考虑催化剂负载量及气化产物分压的影响，建立了煤焦催化水蒸气气化动力学模型，模型预测反应速率常数与实验值误差在10%以内，说明建立的动力学模型可以较好地模拟煤焦的催化水蒸气气化反应过程。
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