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澳大利亚黄土磁学性质及环境意义

Keywords: 澳大利亚黄土,黄土磁化率,磁学性质,磁性矿物溶解转化,全球变化

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Abstract:

澳大利亚内陆广大而干旱,发育着大面积沙漠,却没有多少黄土的报道。本文对惟一报道的黄土,新南威尔士州Mackenzie地区WaterholesCreek剖面进行了详细的采样和磁学参数测量,并与中国黄土高原洛川和西峰经典剖面进行了对比。结果表明该剖面磁学性质与中国黄土高原有许多异同。它成土特征强,百分比频率磁化率较高,但是磁化率值较低,硬磁性矿物含量远远高于中国黄土高原。磁性矿物种类与黄土高原相似,强磁性矿物为磁铁矿和磁赤铁矿,弱磁性矿物为针铁矿/褐铁矿和赤铁矿。但是磁赤铁矿和赤铁矿含量明显少,顺磁性矿物占很大的比例,相对含量高于中国黄土高原。而且,这个比例随深度增加而增高。相对而言,磁赤铁矿对氧化与湿润滞水环境比磁铁矿更为敏感,它在中国洛川黄土剖面随磁化率增加而增多;而在澳大利亚剖面随磁化率增加而减少,表明该剖面成土环境是在磁赤铁矿/磁铁矿不稳定条件下进行的。当地现代年均降水量924.2mm,比洛川高出300mm。可能是因为当地土壤湿度超过磁赤铁矿/磁铁矿临界湿度范围,使其不稳定而被改变成为低磁化率的针铁矿,导致磁化率降低。该剖面普遍可见铁锰质从上部被溶解并迁移到下部沉积,形成铁质胶结和铁质结核,说明成土过程发生了较多水分参与的化学风化。这个过程也导致了原生风积物中强磁化率矿物磁赤铁矿/磁铁矿改变成为铁的氢氧化物(如针铁矿褐铁矿)或者顺磁性矿物,使得磁化率降低。尽管该剖面磁化率大部分与粒度正相关,似乎符合阿拉斯加"风速论"的解释。但剖面下部有明显铁质胶结和结核,说明已经发生了铁的化学风化和物质迁移,"风速论"的前提条件已经不能满足,磁化率变化只能从成土过程寻求解答。

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