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含能材料  2003 

相转移催化硝化四乙酰基二苄基六氮杂异伍兹烷

Keywords: 有机化学,相转移,催化,硝化,六氮杂异伍兹烷

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Abstract:

以相转移催化剂作为助溶剂,采用硝酸铈铵(CAN)和亚硝酸钠在氯仿中氧化TADBIW,在40℃下反应8小时,以66%的得率得到四乙酰基二硝基六氮杂异伍兹烷(TADNIW)。讨论了CAN相转移催化硝化的反应机理。

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