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含能材料  2009 

高氯酸碳酰肼盐与硝酸碳酰肼盐系列化合物的晶格能与感度性能关系(英)

DOI: 10.3969/j.issn.1006-9941.2009.02.017

Keywords: 物理化学,[M(CHZ)3](NO3)2,M(CHZ)3](ClO4)2(M=Mn,Zn,Ni),溶解焓,晶格能,感度

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Abstract:

为了研究晶格能与感度之间的关系,采用微热量计测定了[M(CHZ)3](NO3)2和M(CHZ)3](ClO4)2(M=Mn,Zn,Ni)在去离子水中的溶解焓并计算出它们的标准摩尔溶解焓,根据卡普廷斯基经验公式计算了它们的晶格能,得出配阳离子半径M(CHZ)3]2+(M=Mn,Zn,Ni)分别为2.12?,1.89?和2.70?;讨论了晶格能与机械感度之间的关系:相同外阴离子系列中配合物的晶格能越大,感度越小,并且高氯酸碳酰肼盐要比相应的硝酸碳酰肼盐的晶格能低,感度最高的为[Ni(CHZ)3](ClO4)2,最钝感的为[Zn(CHZ)3](NO3)2。

References

[1]  Campbll,Grzeskowiak.An EPR study of some complexes formed by interaction between salts and carbohydrazide[J].Inorganic and Nuclear Chemistry Letters,1976,12(7):545-549.
[2]  Sindiskii V P,Veridub T Ya,Fogelzang A E.Metal azide complexes with carbohydrazide[J].Russian Journal fo Inorganic Chemistry,1990,35(3):685-688.
[3]  SUN Yuan-hua,ZHANG Tong-lai,ZHANG Jian-guo,et al.The flash pyrolysis of[Zn(CHZ)3](ClO4)2 monitored with T-jump/FTIR spectroscopy[J].Initiators and Pyrotechnics,2005(3):18-21.
[4]  SONG Jiang-chuang,ZHANG Tong-lai,ZHANG Jian-guo,et al.Preparation,crystal structure and thermal decomposition mechanisms of[Ni(NH2NHCO2CH3)3](NO3)2·H2O[J].Acta Chimica Sinica,2003,61(9):1444-1448.
[5]  MA Gui-xia.Researches on preparation and characterisation of nitrate nitrogen-rich coordination compounds[D].Beijing:Beijing Institute of Technology,2005.
[6]  ZHANG Zhi-gang.Researches on perchlorate carbohydrazide energetic coordination compounds[D].Beijing:Beijing Institute of Technology,2001.
[7]  WEI Zhao-rong.Researches on carbohydrazide and its complexes[D].Beijing:Beijing Institute of Technology,1998.
[8]  Bliss D E,Christian S L,Wilson W S.Impact sensitivity of polynitroaromatics[J].Journal of Energetic Materials,1991,9(4):319-348.
[9]  Kapustinkii A F.Lattice energy of ionic crystals[J].Quarterly Reviews of the Chemical Society,1956,10:283-294.

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