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含能材料  2010 

N2O5绿色硝化研究及其新进展

DOI: 10.3969/j.issn.10069941.2010.06.001

Keywords: 有机化学,五氧化二氮,硝化,绿色

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Abstract:

对绿色五氧化二氮在芳烃和氮杂环化合物的硝化反应中的应用进行了详述。五氧化二氮/硝酸体系的硝化能力强，但硝化选择性差，故常用于钝化底物的硝化。五氧化二氮/有机溶剂体系硝化温和，选择性好，主要用于酸敏性和水敏性及含多官能团物质的选择性硝化。同时,对五氧化二氮的合成及放大方法进行了概括。

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