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含能材料  2011 

M(NTO)n·mH2O在水中的溶解行为

DOI: 10.3969/j.issn.1006-9941.2011.02.001

Keywords: 物理化学,,溶解性质,NTO,金属配合物

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Abstract:

借助M(NTO)n·mH2O(M=Ba,n=1,m=3;M=Li,n=1,m=2;M=Ca,n=2,m=4;M=Na,n=m=1;M=Co,Mg,n=2,m=8;M=Ce,Pr,Gd,n=3,m=7;M=Tb,Dy,n=3,m=5;M=Y,Yb,n=3,m=6;NTO=3-nitro-1,2,4-triazol-5-one)的摩尔用量(a)、水溶液浓度(b)及由Calvet微热量计所得的溶解过程热效应(Q)和摩尔溶解焓(ΔdissH),得到了描述这些NTO金属配合物的微分溶解焓(ΔdifHθm)、标准摩尔溶解焓[ΔdissHθm(b=0)]、相对表观摩尔焓(ΔdissHapparent)、相对偏摩尔焓(ΔdissHpartial)和稀释焓(ΔdilH1,2)的5个经验式。

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