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含能材料  2012 

5-氨基-3-硝基-1,2,4-三唑的合成及反应性研究进展

DOI: 10.3969/j.issn.1006-9941.2012.06.012

Keywords: 有机化学,5-氨基-3-硝基-1,2,4-三唑(ANTA),反应位点,高能钝感含能化合物

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Abstract:

氨基-3-硝基-1,2,4-三唑(ANTA)作为一种钝感炸药:撞击感度大于320cm(Type12),密度1.819g·cm-3,爆速约为8460m·s-1,是一种重要的火箭推进剂。同时ANTA具有-NH、-NH2两个活性位点,可参与烷基化、芳基化、重氮化、氧化、离子化等多种反应。本研究概述了ANTA的结构特点,总结了其合成方法,归纳了以ANTA为基不同位点的相关反应及其一般规律,为合成新型低感高能化合物或高氮含能离子盐提供了参考。

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