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含能材料  2015 

CL-20转晶废剂的处理研究

DOI: 10.11943/j.issn.1006-9941.2015.11.021

Keywords: 六硝基六氮杂异伍兹烷(CL-20) 转晶 废剂 烃油 正辛醇 回收

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Abstract:

采用烃油及正辛醇对六硝基六氮杂异伍兹烷(CL-20)转晶废剂进行预处理, 回收CL-20固体, 再利用废剂中各溶剂的沸点不同, 通过共沸蒸馏分离出乙酸乙酯和氯仿等溶剂。利用高效液相色谱(HPLC)、傅里叶变换红外光谱(FTIR)、扫描电镜(SEM)对转晶废剂组分和析出的固体进行了表征。结果表明, 转晶废剂主要含有氯仿、乙酸乙酯、α-CL-20;用烃油处理废剂回收到的α-CL-20的纯度为99.1%, 回收率为79.5%

References

[1]  Wardle B R, Hinshaw J C, Braithwaite P, Synthesis of the caged nitramine HNIW (CL-20)[C]∥Proceedings of the 27th ICT Conference on Propellants,Exposives and Pyrotechnics.Germany,1996.
[2]  欧育湘, 贾会平, 陈博仁, 等.六硝基六氮杂异伍兹烷的研究进展(3)——六硝基六氮杂异伍兹烷晶型研究[J].含能材料,1999,7(2): 49-52.OU Yu-xiang, JIA Hui-ping, CHEN Bo-ren, et al.Research process of hexanitrohexxazaisowurtzitane (3)—— Studies on polymorphs of hexanitrohexxazaisowurtzitane[J].Chinese Journal of Energetic Materials(Hanneng Cailiao), 1999,7(2): 49-52.
[3]  Nielsen A T.Caged polynitramine compound.US, 5693794[P], 1997.
[4]  徐金江, 孙杰, 周克恩, 等.CL-20重结晶过程中的晶型转变研究进展[J].含能材料, 2012,20(2): 248-255.XU Jin-jiang, SUN Jie, ZHOU Ke-en, et al.Review on polymorphic transformation in CL-20 recrystallization[J].Chinese Journal of Energetic Materials(Hanneng Cailiao), 2012,20(2): 248-255.
[5]  欧育湘, 刘进全, 孟征, 等.六硝基六氮杂异伍兹烷转晶工艺最新研究进展[J].含能材料, 2005,13(2): 124-129.OU Yu-xiang, LIU Jin-quan, MENG Zheng, et al.Recent development on crystal transition technology of hexanitrohexaazaiso- wurtzitane[J].Chinese Journal of Energetic Materials(Hanneng Cailiao), 2005,13(2): 124-129.
[6]  Robidoux P Y, Sunahara G I, Savard K, et al.Acute and chronic toxicity of the new explosive CL-20 to the earthworm (Eiseniaandrei) exposed to amended natural soils[J].Environmental Toxicology and Chemistry, 2004,23(4): 1026-1034.
[7]  Dodard S G, Sunahara G I, Kuperman R G, et al.Survival and reproduction of enchytraeid worms, oligochaeta, in different soil types amended with energetic cyclic nitramines[J].Environmental Toxicology and Chemistry,2005,24(10): 2579-2587.
[8]  Kuperman R G, Checkai R T, Simini M, et al.Toxicity of emerging energetic soil contaminant CL-20 to potwormEnchytraeuscrypticus in freshly amended or weathered and aged treatments[J].Chemosphere, 2006,62(8): 1282-1293.
[9]  Simpson R L, Urtiew P A, Ornellas D L, et al.CL-20 performance exceeds that of HMX and its sensitivity is moderate[J].Propellants, Explosives, Pyrotechnics,1997,22(5): 249-255.
[10]  Thiboutot S, Brousseau P, Ampleman G, et al.Potential use of CL-20 in TNT/ETPE-based melt cast formulations[J].Propellants, Explosives, Pyrotechnics, 2008,33(2): 103-108.
[11]  欧育湘, 贾会平, 陈博仁, 等.六硝基六氮杂异伍兹烷四种晶型的晶体结构[J].火炸药学报,1998,21(4): 41-43.OU Yu-xiang, JIA Hui-ping, CHEN Bo-ren, et al.Crystal structure of four polymorphs of hexanitrohexaazaisowurtzitane[J].Chinese Journal of Explosives & Propellants, 1998,21(4): 41-43.
[12]  吴文辉, 王传印, 欧育湘.笼形含能化合物HNIW的结构和性能研究[J].火炸药学报, 2000,23(1): 28-30.WU Wen-hui, WANG Chuan-yin, OU Yu-xiang.Studies on structures and properties of caged energetic compound HNIW[J].Chinese Journal of Explosives & Propellants, 2000,23(1): 28-30.
[13]  OU Yu-xiang, CHEN Bo-ren, JIA Hui-ping.A new energetic material hexanitrohexxazaisowurtzitane[C]∥Proceedings of Sino-Japan Energetic Material Conference,Japan, 1996.
[14]  FoltzM F, Coon C L, Garcia F, et al.The thermal stability of the polymorphs of hexanitrohexaazaisowurtzitane, part Ⅱ[J].Propellants, Explosives, Pyrotechnics,1994,19(3): 133-144.
[15]  程能林.溶剂手册[M].第四版.北京: 化学工业出版社, 2008: 257-693.CHENG Neng-lin.Solvents Handbook [M].Beijing: Chemical Industry Press, 2008: 257-493.
[16]  Torry S A,Cunliffe A V.Polymorphism and solubility of CL-20 in plasticisers and polymers[C]∥31st Int Annual Conf of ICT.Germany, 2000: 107-112.
[17]  Johnston H E, Wardle R B.Process of crystallizing 2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaazatetracyclo[5.5.0.0.5,903,11]-dodecane.US 5874574[P],1999.
[18]  徐金江.CL-20重结晶过程中的晶型转变研究[D].绵阳: 中国工程物理研究院, 2012.XU Jin-jiang.Review on polymorphic transformation in CL-20 recrystallization[D].Mianyang: China Academy of Engineering Physics, 2012.
[19]  宋振伟, 严启龙, 李笑江.溶剂中ε-CL-20的晶型变化[J].含能材料, 2010,6(18): 648-653.SONG Zhen-long, YAN Qi-long, LI Xiao-jiang.Crystal transition of ε-CL-20 in different solvent[J].Chinese Journal of Energetic Materials(Hanneng Cailiao), 2010,6(18): 648-653.
[20]  赵信岐.六硝基六氮杂异伍兹烷四种晶型的Fourier变换红外光谱[J].兵工学报, 1995,16(4): 21-23.ZHAO Xin-qi.FTIR spectra for the α-,β-,γ-, and ε-polymorphs of hexanitrohexaazaisowurtzitane[J].Acta Armamentarii, 1995,16(4): 21-23.
[21]  欧育湘, 陈博仁, 贾会平, 等.六硝基六氮杂异伍兹烷的结构鉴定[J].含能材料, 1995,3(3): 1-7.OU Yu-xiang, CHEN Bo-ren, JIA Hui-ping, et al.Structural identification of hexanitrohexaazaisowurtzitane[J].Chinese Journal of Energetic Materials(Hanneng Cailiao), 1995,3(3): 1-7.
[22]  YAN Qi-long, Svatopluk Zeman, Ahmed Elbeih.The effect of crystal structure on the thermal reactivity of CL-20 and its C4 bonded explosives (I): thermodynamic properties and decomposition kinetics[J].Journal of Thermal Analysis and Calorimetry, 2013,112(2): 823-836.
[23]  Ghosh M, Venkatesan V, Mandave S, et al.Probing Crystal Growth of ε- and α-Cl-20 polymorphs via metastable phase transition using microscopy and vibrational spectroscopy[J].Crystal Growth & Design, 2014,14 (10): 5053-5063.

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