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含能材料  2015 

超细CL-20/TNT共晶炸药的喷雾干燥制备与表征

DOI: 10.11943/j.issn.1006-9941.2015.11.013

Keywords: 六硝基六氮杂异戊兹烷(CL-20) 2,4,6-三硝基甲苯(TNT) 共晶炸药 喷雾干燥 热分解 撞击感度

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Abstract:

采用喷雾干燥法制得超细CL-20/TNT共晶炸药。采用扫描电镜(SEM)对其大小和形貌进行表征, 利用X射线衍射法(XRD)和差示扫描量热法(DSC)对其是否形成共晶进行判定, 并对其进行撞击安全性能测试与分析。结果表明, 所制得的样品不是CL-20与TNT简单的混合, 而是形成了超细CL-20/TNT共晶炸药, 粒径小于1 μm并团聚成1~10 μm的微球; 超细CL-20/TNT共晶炸药的熔点为132.32 ℃, 热分解过程分两个阶段, 第一阶段和第二阶段的分解放热峰温分别为218.98 ℃和253.15 ℃, 特性落高为49.3 cm, 比原料CL-20高36.2 cm

References

[1]  Ravi P, Badgujar D M, Gore G M, et al.Review on melt cast explosives[J].Propellants, Explosives, Pyrotechnics, 2011,36(5): 393-403.
[2]  Thiboutot S, Brousseau P, Ampleman G, et al.Potential use of CL-20 in TNT/ETPE-based melt cast formulations[J].Propellants, Explosives, Pyrotechnics, 2008,33(2): 103-108.
[3]  Yang Z W, Li H Z, Huang H, et al.Preparation and performance of a HNIW/TNT cocrystal explosive[J].Propellants, Explosives, Pyrotechnics, 2013,38(4): 495-501.
[4]  Bolton O, Matzger A J.Improved stability and smart-material functionality realized in an energetic cocrystal[J].Angewandte Chemie International Edition, 2011,50(38): 8960-8963.
[5]  曾贵玉,郁卫飞,聂福德,等.超细炸药粉体性能及其应用研究进展[J].含能材料,2005,13(5): 349-353.ZENG Gui-yu, YU Wei-fei, NIE Fu-de, et al.Review on properties of ultrafine explosives powder and its application[J].Chinese Journal of Energetic Materials(Hanneng Cailiao), 2005,13(5): 349-353.
[6]  Armstrong R W, Baschung B, Booth D W, et al.Enhanced propellant combustion with nanoparticles[J].Nano Letters, 2003,3(2): 253-255.
[7]  Wang J Y, Huang H, Xu W Z, et al.Prefilming twin-fluid nozzle assisted precipitation method for preparing nanocrystalline HNS and its characterization[J].Journal of Hazardous Materials, 2009,162(2-3): 842-847.
[8]  Sivabalan R, Gore G M, Nair U R, et al.Study on ultrasound assisted precipitation of CL-20 and its effect on morphology and sensitivity[J].Journal of Hazardous Materials, 2007, A139: 199-203.
[9]  Qiu H W, Stepanov V, Di Stasio A R, et al.RDX-based nanocomposite microparticles for significantly reduced shock sensitivity[J].Journal of Hazardous Materials, 2011,185(1): 489-493.
[10]  Qiu H W, Stepanov V, Chou T, et al.Single-step production and formulation of HMX nanocrystals[J].Powder Technology, 2012,226: 235-238.
[11]  Shi X F, Wang J Y, Li X D, et al.Preparation and characterization of HMX/Estane nanocomposites[J].Central European Journal of Energetic Materials, 2014,11(3): 433-442.
[12]  An C W, Li H Q, Geng X H, et al.Preparation and properties of 2,6-diamino-3,5-dinitropyrazine-1-oxide based nanocomposites[J].Propellants, Explosives, Pyrotechnics, 2013,38(2): 172-175.
[13]  Alhalaweh A, Velaga S P.Formation of cocrystals from stoichiometric solutions of incongruently saturating systems by spray drying[J].Crystal Growth & Design, 2010,10(8): 3302-3305.
[14]  Alhalaweh A, Kaialy W, Buckton G, et al.Theophylline cocrystals prepared by spray drying: physicochemical properties and aerosolization performance[J].AAPS Pharm Sci Tech, 2013,14(1): 265-276.
[15]  杨宗伟,张艳丽,李洪珍,等.CL-20/TNT共晶炸药的制备、结构与性能[J].含能材料,2012,20(6): 674-679.YANG Zong-wei, ZHANG Yan-li, LI Hong-zhen, et al.Preparation, structure and properties of CL-20/TNT cocrystal[J].Chinese Journal of Energetic Materials(Hanneng Cailiao), 2012,20(6): 674-679.
[16]  欧育湘, 炸药学[M].北京: 北京理工大学出版社, 2006: 264-270.OU Yu-xiang.Explosive Scinece[M].Beijing: Beijing Institute of Technology Press, 2006: 264-270.
[17]  国防科学技术工业委员会.GJB 772A-1997,炸药试验方法[S].北京: 国防科工委军标出版社,1997: 201-206.
[18]  Ampleman G, Brousseau P, Thiboutot S, et al.Evaluation of GIM as a greener insensitive melt-cast explosive[J].International Journal of Energetic Materials and Chemical, 2012,11(1): 59-87.

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