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含能材料  2015 

四环庚烷的制备及自燃性

DOI: 10.11943/j.issn.1006-9941.2015.10.008

Keywords: 化学工艺 四环庚烷(QC) 液体推进剂 点火延迟 自燃性

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Abstract:

具有高张力和笼状结构的四环庚烷(QC)是很具潜力的自燃类碳氢燃料。研究了无溶剂条件下公斤级QC的合成工艺。测试了QC/白色发烟硝酸(WFNA)和QC/N2O4的自燃性能。结果表明,反应16 h和分离提纯后,QC产品的纯度和收率能分别达到99.5%和96.2%, 单批产量为2 kg, QC/WFNA和QC/N2O4的点火延迟时间分别为98 ms和29 ms。固体纳米颗粒的添加能促进自燃性能, 纳米硼、碳、铝可缩短点火延迟时间, 添加质量分数为0.25%的纳米硼/碳/铝后点火延迟时间分别为68/73/75 ms(发烟硝酸)和18/27/33 ms(N2O4),证明QC可作自燃类高能液体推进剂使用

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