全部 标题 作者
关键词 摘要

OALib Journal期刊
ISSN: 2333-9721
费用:99美元

查看量下载量

相关文章

更多...
含能材料  2015 

N,N′-二(三硝基乙基)-5,6-二氨基呋咱并[3,4-b]吡嗪(DNFP)的合成与性能

DOI: 10.11943/j.issn.1006-9941.2015.02.005

Keywords: 吡嗪 三硝基乙基 爆轰性能 N,N′-二(三硝基乙基)-5,6-二氨基呋咱并[3,4-b]吡嗪(DNFP)

Full-Text   Cite this paper   Add to My Lib

Abstract:

以5,6-二羟基呋咱并[3,4-b]吡嗪(DHFP)为原料, 经氯代、胺化、N-羟甲基化反应、缩合得到N,N′-二(三硝基乙基)-5,6-二氨基呋咱并[3,4-b]吡嗪(DNFP), 产率为31%。采用IR、1H NMR、13C NMR、元素分析对其结构进行了表征。探讨了DNFP的合成反应机理及反应条件。采用密度泛函理论B3LYP/6-311G(d, p)方法计算了DNFP的生成焓。同时利用Kamlet-Jacobs公式预测其爆热, 爆速, 爆压分别为: 6714 J·g-1, 8.91 km·s-1, 36 GPa

References

[1]  阳世清,徐松林,黄亨健,等.高氮化合物及含能材料[J].化学进展,2008,20(4): 526-536.YANG Shi-qing, XU Song-lin, HUANG Heng-jian, et al.High nitrogen compounds and their energy materials[J].Progress in Chemistry, 2008,20(4): 526-536.
[2]  罗义芬, 王伯周, 陈晓芳, 等.1,3,4,6-四硝基吡唑[4,3-c]并吡唑(TNPP)合成[J].含能材料,2012,20(6): 814-815.LUO Yi-fen, WANG Bo-zhou, CHEN Xiao-fang, et al.Synthesis of 1,3,4,6-tetranitropyrazole[4,3-c] pyrazole(TNPP)[J].Chinese Journal of Energetic Materials(Hanneng Cailiao), 2012,20(6): 814-815.
[3]  贾思媛, 张海昊, 王伯周, 等.3,4-双(3′-氨基呋咱-4′-基)呋咱的合成与表征[J].含能材料, 2013,21(3): 289-293.JIA Si-yuan, ZHANG Hai-hao, WANG Bo-zhou, et.al.Synthesis and characterization of 3,4-bis-(3′-aminofurazal-4′-yl)-furzan(BATF)[J].Chinese Journal of Energetic Materials(Hanneng Cailiao), 2013,21(3): 289-293.
[4]  Nivikova T S, Meinikova T M, Khari-tonova O V, et al.An effective method for the oxidation of aminofurazans to nitrofurazans[J].Mendeleev Communication, 1994,4(4): 138-140.
[5]  Sheremeteev A B.Chemistry of furazan fused to five me-mbered rings[J].Journal of Heterocyclic Chemistry, 1995,32(2): 371-385.
[6]  YIN Ping, ZHANG Qing-hua, ZHANG Jia-heng, et al.N-Trinitroethylamino functionalization of nitromidazoles:a new strategy for high performance energetic materials[J].Journal of Materials Chemistry, 2013,1(25), 7500-7510.
[7]  Margarita A E, Igor V O, Alexander S K, et al.Henry and mannich reactions of polynitroalkes in ionic liquids [J].Mendeleev Commun, 2011,21(1): 21-23.
[8]  Avdonin V V, Volkov G A, Galkin P V, et al.Preparation and properties of N-fluoro-and N-nitrobis(2,2,2-trinitroethyl)ureas[J].Izvestiya Akademii Nauk Seriya Khimicheskaya, 1992,8: 1857-1863.
[9]  Ovchinnikov I V, Kulikov A S, Epishina M A, et al.Synthesis of N-trinitroethyl derivatives of linear and heterocyclic nitrogen-containing compound[J].Russian Chemical Bulletin, 2005,54(5): 1346-1349.
[10]  Jaidann M, Roy S.A DFT theoretical study of heats of formation and detonation properties of nitrogen-rich explosives[J].Journal Hazard Materials, 2010,176: 165-173.
[11]  PAN Yong, LI Jin-shan, CHENG Biao, et al.Computational studies on the heats of formation, energetic properties, and thermal stability of energetic nitrogen-rich furazano[3,4-b]pyrazine-based derivatives[J].Computational and Theoretical Chemistry, 2012,992: 110-119.
[12]  ZHANG Qing-hua, ZHANG Jia-heng, Damon A P, et al.Energetic N-Trinitrmethyl-substituted mono-, di-, and triaminotetrazoles[J].Chemistry European Journal, 2013,19(33): 11000-11006.
[13]  Michael G, Thomas M K.Development and testing of energetic materials: the concept of high densities based on the trinitroethyl functionality[J].Advanced Functional Materials, 2009,19(3): 347-365.
[14]  Srarchenkov I B, Andrianov V G, Mishnev A F.The chemistry of furazano[3,4-b]pyrazine: properties of 5,6-diamino-and 5,6-dihydrazinofurazinofurazano[3,4-b]pyrazine[J].Chemistry of Heterocyclic Compounds,1999,35(4): 499-508.
[15]  WU Qiong, ZHU Wei-hua, XIAO He-ming.Molecular design of tetrazole-and tetrazine-based high-density energy compounds with oxygen balance equal to zero[J].Journal of Chemical & Engineering Date, 2013,58(10): 2748-2762.
[16]  Aleksei B S, Nataly S A, Nadezhda V P, et al.Ionic liquids as unique solvents in one-pot synthesis of 4-(N, 2,2,2-Tetranitroethylamino)-3-R-Furazans[J].Chemistry European Journal, 2013,19(37): 12446-12457.
[17]  ZHANG Xiao-wen, ZHU Wei-hua, XIAO He-ming.Comparative theoretical studies of energetic substituted carbon- and nitrogen-bridged difurazans[J].The Journal of Physical Chemistry A, 2010,114(1): 603-612.
[18]  Caflisch R E.Monto carto and quasi-monto carto methods[J].Acta Numerica, 1998,7: 1-49.
[19]  Kamlet M J, Jacobs S J.Chemistry of detonationⅠ: a simple method for calculating detonation properties of C H N O explosives[J].Journal of Chemistry Physics, 1968,48(1): 23-25.
[20]  Talawar M B, Sivabalan R, Mukundan T, et al.Environmentally compatible next generation green energetic materials[J].Journal Hazard Material, 2009,161:589-607.

Full-Text

Contact Us

service@oalib.com

QQ:3279437679

WhatsApp +8615387084133