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含能材料  2002 

单体炸药撞击感度的理论判别——从热力学判据到动力学判据

Keywords: 单体炸药,撞击感度,热解活化能,键级,前线轨道能级

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Abstract:

评介了系列爆炸物撞击感度相对大小的量子化学理论判据;包括“最小键级原理(PSBO)”和“最易跃迁原理(PET)”——热力学判据;重点介绍“热解引发反应活化能”动力学判据。比较了它们的优劣和适用性。

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