四乙酰基二硝基六氮杂异伍兹烷的合成与表征
Keywords: 有机化学,四乙酰基二硝基六氮杂异伍兹烷(TADN),合成,表征,X-射线衍射
Abstract:
简便易行地合成了CL-20的中间体四乙酰基二硝基六氮杂异伍兹烷（TADN）,收率达90%。TADN属于单斜晶系，P21/n空间群，晶体学参数为：a＝1.12231(8)nm，b=1.41083(10)nm，c=1.12331(8)nm，Z=4，V=1.7395(2)nm3，dc=1.628g·cm-3，β=102.039(2)°。
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