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含能材料  2006 

1-(对二甲氨基苯基)五唑的合成研究

Keywords: 应用化学,多氮化合物,五唑,合成

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Abstract:

利用对二甲氨基苯胺盐酸盐和亚硝酸钠反应得到对二甲氨基苯基重氮盐,低温下与叠氮化钠反应制得1-(对二甲氨基苯基)五唑。采用低温核磁共振氢谱(1HNMR)对目标化合物进行了表征,利用程序升温核磁共振分析了温度变化时目标化合物在溶剂体系中的稳定性,并对五唑衍生物的生成及分解机理进行了讨论。

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