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含能材料  2009 

钴(Ⅲ)配合物[Co(NH3)4(N3)2]ClO4晶体结构及激光化学感度

DOI: 10.3969/j.issn.1006-9941.2009.06.013

Keywords: 物理化学,钴(Ⅲ)配合物,晶体结构,激光化学感度

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Abstract:

制备了高氯酸·四氨·双叠氮基合钴(Ⅲ)(DACP)的单晶,用X-ray单晶面探衍射仪测定了其晶体结构。结果表明,晶体属三斜晶系,空间群为P-1。晶体学参数为:a=0.74229(9)nm,α=93.244(2)°;b=1.2127314)nm,β=100.074(2)°;c=1.8124(2)nm,γ=98.033(2)°。晶胞体积V=1.5851(3)nm3,晶胞分子数Z=6,计算密度Dc=1.952mg·mm-3,线性吸收系数μ=1.901mm-1,单胞中电子数目F(000)=948。该化合物对635nm的激光非常敏感。

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