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含能材料  2011 

富勒烯制备与分离方法研究进展

DOI: 10.3969/j.issn.1006-9941.2011.05.025

Keywords: 有机化学,富勒烯,制备,分离,提纯

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Abstract:

对富勒烯(Fullerene)的制备与分离提纯方法进行了概述。分析了电弧法、激光蒸发石墨法、等离子体蒸发石墨法、苯燃烧法、催化热分解法及爆炸辅助气相沉积法制备富勒烯等方法的优缺点,认为,富勒烯的制备过程中受到反应区温度、压强、退火温度、催化剂和保护气体等多种因素的影响。综合评估几种方法,认为苯燃烧法成本优势较明显,是国际上工业化生产的主流方法。分离与提纯是富勒烯生产的关键和难点,〖JP2〗目前的分离与提纯方法成本高、效率低,寻找快速有效的富勒烯分离和提纯方法十分重要。

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