全部 标题 作者
关键词 摘要

OALib Journal期刊
ISSN: 2333-9721
费用:99美元

查看量下载量

相关文章

更多...
含能材料  2011 

一类重要含能材料:5-取代四唑含能金属配合物

DOI: 10.3969/j.issn.1006-9941.2011.05.024

Keywords: 有机化学,含能材料,5-取代四唑金属含能配合物(TEMCs),四唑配体,综述

Full-Text   Cite this paper   Add to My Lib

Abstract:

分类综述了5-取代四唑金属含能配合物(TEMCs)的合成及研究进展。目前,国内外关于TEMCs的研究不多,其中以5-氰基四唑(CT)、5-硝基四唑(NT)、5-氨基四唑(AT)为配体的TEMCs因其优越的性能和突出的特点,成为含能材料领域研究的重要方向。经过调研、分析,得出如下结论:①TEMCs的合成步骤较少、反应条件温和、易于操作和控制、产率高,且环境友好,但对其结构与性能的研究较困难,特别是对其固态摩尔生成焓的探究没有文献报道;②可通过改变外阳离子或中心金属离子、调控配合物分子中配体数目、调控合成过程等方式寻找性能优良的TEMCs;③通过有目的的设计和选择合适的配体与金属离子以及控制反应条件等因素来系统研究配合物的结构与性能,对指导实验研究具有重要意义。

References

[1]  Huynh M H V. Explosive complexes: US 007592462 B2[P],2009.
[2]  Huynh M H V. Preparation of terazole derivatives: US 2008/0200687 A1[P],2008.
[3]  Huynh M H,Michael A H,Thomas J M,et al. Green primaries: Environmentally friendly energetic complexes[C]∥Proceedings of the National Academy of Sciences,USA,2006,14: 5409-5412.
[4]  Huynh M H,Michael D C,Thomas J M,et al. Green primary explosives: 5-Nitrotetrazolato-N2-ferrate hierarchies[C]∥Proceedings of the National Academy of Sciences,USA,2006,27: 10322-10327.
[5]  Huynh M H. Simulant material for primary explosives: US 2009/019993 A1[P],2009.
[6]  Hiskey M A,Huynh M H. Primary explosives: US 007875725 B2[P],2011.
[7]  Hiskey M A,Huynh M H. Explosive complexes: US 2010/0063295 A1[P],2010.
[8]  Huynh M H. Lead-free primary explosives: US 2008/0091029[P],2008.
[9]  焦宝娟. 双四唑类过渡金属含能配合物的合成及性质研究[D]. 西安: 西北大学,2007.
[10]  蒋琪英,沈娟,钟国清,等. 含能配合物研究进展[J]. 现代化工,2006,26: 24-26.JIANG Qi-ying,SHEN Juan,ZHONG Guo-qing,et al. Progress of study in energetic coordination complexes[J]. Modern Chemical Industry,2006,18: 24-27.
[11]  侯向阳,焦宝娟,范广,等. 含能配合物M(ATZ)·nH2O液相生成反应的热动力学研究[J]. 延安大学学报(自然科学版),2008,27: 41-47.HOU Xiang-yang,JIAO Bao-juan,FAN Guang,et al. Thermodynamic studies on liquid phase reaction of energetic complexes M(ATZ)·nH2O[J]. Journal of Yan′an University,2008,27: 41-47.
[12]  刘晓建,张慧娟,林秋汉,等. 唑类含能离子化合物的合成研究进展[J]. 火炸药学报,2010(1): 6-10.LIU Xiao-jian,ZHANG Hui-juan,LIN Qiu-han,et al. Progress of study on the synthesis of azole energetic ionic compounds[J]. Chinese Journal of Explosives & Propellants,2010(1): 6-10.
[13]  齐书元,张建国,张同来,等. 含能配合物[Mn(DAT)6](ClO4)2的合成、晶体结构、热行为及感度性质[J]. 高等学校化学学报,2009,30: 1935-1939.QI Shu-yuan,ZHANG Jian-guo,ZHANG Tong-lai,et al. Synthesis,crystal structure,thermal behavior and sensitivity properties of new energetic compound [Mn(DAT)6](ClO4)2[J]. Chemical Journal of Chinese Universities,2009,30: 1935-1939.
[14]  Zhilin A Y,Ilyushin M A,Tselinskii I V,et al. Synthesis and properties of tetraamminebis(1-methyl-5-aminotetrazole-N3,N4)cobalt(Ⅲ) perchlorate[J]. Russian Journal of Applied Chemistry,2002,75: 1849-1851.
[15]  Zhilin A Y,Ilyushin M A,Tselinskii I V,et al. High-energy-capacity cobalt(Ⅲ) tetrazolates[J]. Russian Journal of Applied Chemistry,2003,76: 572-576.
[16]  Ivashkevich O A,Matulis Vad E,Matulis V E,et al. Quantum chemical study of electronic and steric structure of vinyltetrazoles: Ⅰ. 2-Substituted 5-vinyltetrazoles[J]. Russian Journal of Applied Chemistry,2004,74: 134-140.
[17]  Ivashkevich O A,Matulis Vad E,Matulis Vit E,et al. Quantum-chemical study of the electronic and Steric structure of vinyltetrazoles: Ⅱ.1 2-Vinyltetrazoles[J]. Russian Journal of Applied Chemistry,2004,74: 409-413.
[18]  〖JP4〗Galvez-Ruiz J C,Holl G,Karaghiosoff K,et al. Derivatives of 1,5-diamino-1H-tetrazole: A new family of energetic heterocyclic-nased salts[J]. Inorganic Chemistry,2005,44: 4237-4253.〖JP〗 
[19]  Klaptke T M,Sabaté C M. Bistetrazoles: nitrogen-rich,high-performing,insensitive energetic compounds[J]. Chemistry of Materials,2008,20: 3629-3637.
[20]  Klaptke T M,Sabaté C M. Nitrogen-rich tetrazolium azotetrazolate salts: A new family of insensitive energetic materials[J]. Chemistry Materials,2008,20: 1750-1763.
[21]  Majano G,Mintova S,Bein T,et al. Confined detection of high-energy-density materials[J]. The Journal of Physical Chemistry,2007,111: 6694-6699.
[22]  〖JP4〗Karaghiosoff K,Klaptke T M,Mayer P,et al. N-nitroso- and N-nitraminotetrazoles[J]. The Journal of Organic Chemistry,2006,71: 1295-1305.〖JP〗
[23]  Klaptke T M,Mayer P,Schulz A,et al. 1,5-Diamino-4-methyltetrazolium dinitramide[J]. Journal of the American Chemical Society,2005,127: 2032-2033.
[24]  Talawar M B,Chhabra J S,Agrawal A P,et al. Synthesis,characterization,thermolysis and performance evaluation of mercuric-5-nitrotetrazole (MNT)[J]. Journal of Hazardous Materials,2004,A113: 27-23.
[25]  Talawar M B,Sivabalana R,Senthilkumar N G,et al. Synthesis,characterization and thermal studies on furazan- and tetrazine-based high energy materials[J]. Journal of Hazardous Materials,2004,A113: 11-25.
[26]  Muthurajan H,Sivabalan R,Talawar M B,et al. Primary explosives: Electrostatic discharge initiation,additive effect and its relation to thermal and explosive characteristics[J]. Journal of Hazardous Materials,2006,113: 30-36.
[27]  Talawar M B,Agrawal A P,Anniyappan M. Primary explosives: Electrostatic discharge initiation,additive effect and its relation to thermal and explosive characteristics[J]. Journal of Hazardous Materials,2006,B137: 1074-1078.
[28]  Talawar M B,Agrawal A P,Asthana S N. Energetic co-ordination compounds: Synthesis,characterization and thermolysis studies on bis-(5-nitro-2H-tetrazolato-N2) tetraammine cobalt(Ⅲ) perchlorate (BNCP) and its new transition metal (Ni/Cu/Zn) perchlorate analogues[J]. Journal of Hazardous Materials,2005,A120: 25-35.
[29]  Muthurajana H,Sivabalanb R,Saravananb N P,et al. Computer code to predict the heat of explosion of high energy materials[J]. Journal of Hazardous Materials,2009,161: 714-717.
[30]  Talawar M B,Sivabalan R,Mukundan T,et al. Environmentally compatible next generation green energetic materials (GEMs)[J]. Journal of Hazardous Materials,2009,161: 589-607.
[31]  Talawar M B,Chhabra J S,Agrawal A P,et al. Synthesis,characterization,thermolysis and performance evaluation of mercuric-5-nitrotetrazole (MNT)[J]. Journal of Hazardous Materials,2004,113: 27-33.
[32]  Gaponik P N,Voitekhovich S V,Ivashkevich O A. For a recent review of metal tetrazolate complexes[J]. Russian Chemistry Review,2006,75: 507-539.
[33]  Sergei V V,Tatiyana V S,Alexander S L,et al. Copper(Ⅱ),palladium(Ⅱ) and platinum(Ⅱ) chloride complexes with 5-amino-2-tert-butyltetrazole: Synthesis,characterization and cytotoxicity[J]. Polyhedron,2009,28: 3614-3620.
[34]  Selma P,Dongmei L,Mary J H,et al. Synthesis and structural characterization of heavier group 1 methyl tetrazolate complexes: New bridging coordination modes of the tetrazolate ligand[J]. Polyhedron,2008,27: 3280-3286. 
[35]  肖鹤鸣,陈兆旭. 四唑化学的现代理论[M]. 北京: 科技出版社,2002: 216-263 .XIAO He-ming,CHEN Zhao-xu. Modern Theory of Tetrazole Chemistry[M]. Beijing: Science and Technology Press,2002: 216-263 .
[36]  McGinley J,Fleming A. Synthesis of macrocycles containing tetrazole units-potential metal complexation sites[J]. Chemistry and Materials Science,2008,61: 1-10.
[37]  Klapotke T M,Sabate C M,Stierstorfer J. Neutral 5-nitrote-trazoles: Easy initiation with low pollution[J]. New Journal of Chemistry,2009,33: 136-147.
[38]  Hartdegen V,Klaptke T M,Sproll S M. Tetrazole-5-carboxylic acid based salts of earth alkali and transition metal cations[J]. Inorganic Chemistry,2009,48: 9549-9556.
[39]  Voitekhovich S V,Talapin D V,Klinke C. CdS nanoparticles capped with 1-substituted 5-thiotetrazoles: Synthesis,characterization,and thermolysis of the surfactant[J]. Chemistry Materials,2008,20: 4545-4547.
[40]  Tappan B C,Huynh M H,Hiskey M A,et al. Ultralow-density nanostructured metal foams: Combustion synthesis,morphology,and composition[J]. Journal of the American Chemical Society,2006,128: 6589-6594.
[41]  Horike S,Dinca M,Tamaki K,et al. Size-selective lewis acid catalysis in a microporous metal-organic framework with exposed Mn2+ coordination sites[J]. Journal of the American Chemical Society,2008,130: 5854-5855.
[42]  Koldobskii G I,Ostrovskii V A. Tetrazoles[J]. Russian Chemical Reviews,1994,63: 797-814.
[43]  Zhilin A Y,Ilyushin M A,Tselinskii I V. Reaction of cobalt(Ⅲ) diaquatetrammine cation with 5-(3-nitrophenyl)-tetrazole[J]. Russian Journal of General Chemistry,2001,71: 664-3667. 
[44]  李志敏,张建国,张同来,等. 硝基四唑及其高氮化合物[J]. 化学进展,2010,22: 639-647.LI Zhi-min,ZHANG Jian-guo,ZHANG Tong-lai,et al. Nitro-tetrazole and its high nitrogen-contented compounds[J]. Progress in Chemistry,2010,22: 639-647.
[45]  〖JP3〗Cui Y,Zhang J G,Zhang T L,et al. Synthesis,structural investigation,thermal decomposition mechanism and sensitivity properties of an energetic compound [Cd(DAT)6](ClO4)2(DAT=1,5-diaminotetrazole)[J]. Journal of Hazardous Materials,2008,160: 45-50.〖JP〗
[46]  Cui Y,Zhang J G,Zhang T L,et al. Synthesis,structural investigation and thermal analyses of a novel coordination compound [Cd(DAT)6](HTNR)2·3.5H2O(DAT=1,5-diaminotetrazole,H2TNR=styphnic acid)[J]. Journal of Molecular Structure,2008,889: 177-185.〖JP〗
[47]  Cui Y,Zhang J G,Zhang T L,et al. Preparation,crystal structure and thermal analyses of a nitrogen-rich coordination compound [Co(DAT)6](PA)2·4H2O[J]. Chinese Journal of Chemistry,2008,26: 2029-2034.
[48]  尚静,张建国,崔燕,等. 含能配合[Zn(DAT)6](ClO4)2 (DAT=1,5-二氨基四唑)的合成、晶体结构及性质[J]. 化学学报,2010,68: 233-238.SHANG Jing,ZHANG Jian-guo,CUI Yan,et al. Synthesis,crystal structure,and properties of an energetic compound [Zn(1,5-diaminotetrazole)6](ClO4)2[J]. Acta Chimica Sinica,2010,68: 233-238. 
[49]  冯金玲,张建国,李志敏,等. 高氮含能配合物[Co(AZT)2·(H2O)4](HTNR)2·4H2O的合成、晶体结构及性质[J]. 化学学报,2010,68: 2493-2499.FENG Jin-ling,ZHANG Jian-guo,LI Zhi-min,et al. Synthesis,crystal structure and properties of a novel high-nitrogen energetic complex [Co(AZT)2·(H2O)4](HTNR)2·4H2O[J]. Acta Chimica Sinica,2010,68: 2493-2499.
[50]  李志敏,张同来,杨利,等. 配位聚合物{[Cu2(nbdo)2 ·( H2O)2]·2(H2O)}n的热稳定性以及荧光性能和储氢性能[J]. 化学研究,2010(4): 10-26.LI Zhi-min,ZHANG Tong-lai,YANG Li,et al. Thermal stability plus luminescence property an hydrogen-storage capacity of coordination polymer {[Cu2(nbdo)2· ( H2O)2]·2(H2O)}n[J]. Chemical Research,2010(4): 10-26.
[51]  盛涤伦,马凤娥,孙飞虎,等. BNCP起爆药的合成及主要性能[J]. 含能材料,2000,8(3): 100-103.SHENG Di-lun,MA Feng-e,SUN Fei-hu,et al. Study on synthesis and main properties of BNCP[J]. Chinese Journal of Energetic Materials(Hanneng Cailiao),2000,8(3): 100-103.
[52]  盛涤伦,马凤娥,张裕峰,等. 高氯酸·四氨·双(5-硝基四唑)合钴(Ⅲ)(BNCP)的晶体结构[J]. 含能材料,2007,15(5): 511-514.SHENG Di-lun,MA Feng-e,ZHANG Yu-feng,et al. Crystal structure of initiating explosive BNCP[J]. Chinese Journal of Energetic Materials(Hanneng Cailiao),2007,15(5): 511-514.
[53]  刘自汤,劳允亮. 起爆药实验[M]. 北京: 北京理工大学出版社,1995: 101-105.LIU Zi-tang,LAO Yun-liang. Experiments of Primary Explosives[M]. Beijing: Beijing Institute Technology Press,1995: 101-105.
[54]  舒远杰. 高能硝胺炸药的热分解[M]. 北京: 国防工业出版社,2010: 99-102 .〖KG2*2〗SHU Yuan-jie. Thermal Decomposition of Nitramine High Explosives[M]. Beijing: National Defense Industry Press,2010: 99-102 .
[55]  张蕊,冯长根,姚朴,等. 钝感起爆药BNCP 的热安全性[J]. 火炸药学报,2003,26: 66-69.ZHANG Rui,FENG Chang-gen,YAO Pu,et al. The thermal safety of a new kind of initiating explosives BNCP[J]. Chinese Journal of Explosives & Propellants,2003,26: 66-69.
[56]  周建华,程碧波,李金山,等. 高氯酸[四氨·双(5-硝基四唑)]合钴(Ⅲ)的热分解性能[J]. 火炸药学报,2008,31: 64-66.ZHOU Jian-hua,CHENG Bi-bo,LI Jin-shan,et al. Thermal decomposition property of BNCP[J]. Chinese Journal of Explosives & Propellants,2008,31: 64-66.
[57]  张苏杭,韩琳,王新德. 5-氨基四唑及其衍生物的合成和应用综述[J]. 洛阳师范学院学报,2006(5): 74-78.ZHANG Shu-hang,HAN Lin,WANG Xin-de. Review of synthesis and application of 5-aminotetrazole and 5-ATZ derivatives[J]. Luoyang Normal University,2006(5): 74-78.
[58]  Lund G K,Blau R J. Anhydrous 5-aminotetrazole gas generant compositions and methods of preparation: US 5500059[P],1996.
[59]  Lesnikovich A I,Ivashkevich O A,Levchik,et al. Thermal decomposition of aminotetrazoles[J]. Thermochimica Acta,2002,388: 233-51.
[60]  Gaponik P N,Voitekhovich S V,Lyakhov A S,et al. Crystal structure and physical properties of the new 2D polymeric compound bis(1,5-diaminotetrazole)dichlorocopper(Ⅱ)[J]. Inorganica Chimica Acta,2005,358: 2549-2557.
[61]  Konkova T S,Matyushin Y N. Thermochemistry of transition metal complexes with 1,5-diaminotetrazole[C]∥31th Int Ann Conf ICT,Germany,Karlsruhe,2000. 
[62]  Smirnov A V,Ilyushin M A,Tselinskii I V. Synthesis of cobalt(Ⅲ) ammine complexes as explosives for safe priming charges[J]. Russian Journal of Applied Chemistry,2004,77: 794-796.

Full-Text

Contact Us

service@oalib.com

QQ:3279437679

WhatsApp +8615387084133