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含能材料  2012 

二硝基羟基吡啶类含能盐的研究进展

DOI: 10.3969/j.issn.1006-9941.2012.01.030

Keywords: 有机化学,3,5-二硝基羟基吡啶,合成,晶体结构,研究进展

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Abstract:

综述了国内外关于三种3,5-二硝基羟基吡啶类化合物(2-羟基-3,5-二硝基吡啶(2HDNP)、4-羟基-3,5-二硝基吡啶(4HDNP)和4-羟基-3,5-二硝基吡啶氮氧化物(4HDNPO))金属盐和非金属盐的合成、晶体结构、热化学性质和非等温热分解动力学行为，以及它们对固体推进剂燃烧性能影响的研究进展。三种3,5-二硝基羟基吡啶类化合物铅铜盐都表现出对RDX-CMDB微烟推进剂明显的催化燃烧作用和降低压力指数的能力，其中以2HDNPPb/2HDNPCu复合催化体系催化效果最好。预计随着更多此类化合物及其含能盐的合成及应用研究，会发现一些综合性能优良的固体推进剂燃速调节剂。

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