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含能材料  2012 

FOX-7的反应性研究进展

DOI: 10.3969/j.issn.1006-9941.2012.01.029

Keywords: 应用化学,1,1-二氨基-2,2-二硝基乙烯(FOX-7),硝基烯胺,有机合成,合成机理

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Abstract:

基于新型含能材料1,1-二氨基-2,2二硝基乙烯(FOX-7)特殊的“推-拉”硝基烯胺结构,总结了FOX-7所能发生的化学反应,包括酸碱反应、配位反应、亲核取代、酰基化反应、氧化反应、还原反应、水解反应、氨基的亲电加成反应、叠氮反应等,从而分析了碳碳双键、氨基部分及硝基部分的反应性能,并讨论了相应的反应路线和反应机理。

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