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含能材料  2013 

一种合成3,3′-二氨基-4,4′-氧化偶氮呋咱的新方法

Keywords: 有机化学,3,3′-二氨基-4,4′-氧化偶氮呋咱,3-氨基-4-甲酰胺基呋咱,3,4-二甲酰胺基呋咱,合成

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Abstract:

以3,4-二氨基呋咱为原料,经过中间体3-氨基-4-甲酰胺基呋咱或3,4-二甲酰胺基呋咱,以1,4-二氧六环为溶剂,30%双氧水为氧化剂,加热回流4h,得到产物3,3′-二氨基-4,4′-氧化偶氮呋咱(DAOAF),产率分别为97%或89%。并通过1HNMR、13CNMR、IR和EI对产物进行了表征。

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