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含能材料  2014 

B(N3)3的简便合成方法

DOI: 10.3969/j.issn.1006-9941.2014.05.027

Keywords: 无机化学,多叠氮化合物,三叠氮化硼B(N3)3,合成,表征

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Abstract:

以三溴化硼和三甲基叠氮硅烷为起始原料,以乙腈为溶剂,经过低温反应在液相中合成了三叠氮化硼(B(N3)3),并通过蒸馏分离出淡黄色液体样品,产物通过傅里叶变换红外光谱和14NNMR进行了表征,实现了B(N3)3的简便合成。

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