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含能材料  2014 

几类低价态铝簇配合物的结构特征研究进展

DOI: 10.3969/j.issn.1006-9941.2014.04.025

Keywords: 无机化学,含能材料,铝簇,前驱体,配体,结构特征

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Abstract:

低价态铝簇配合物中金属铝的价态介于0价和+3价之间,含有丰富的Al—Al金属键和Al—R配位键,为合成具有特定性能的新型富金属材料提供了新思路。详细地介绍了低价态铝簇配合物前驱体AlX(X=F,Cl,Br,I)的制备工艺,并系统地评述了国内外一些低价态铝簇配合物的研究进展,主要为金属有机铝簇配合物、非金属铝簇配合物和具有jellium模型结构的Alm-n铝簇配合物,分别从形成机理、配位模式、性能特征、原子特征等多方面分析了铝簇配合物的结构特征。认为,选用合适的配体与低价态铝簇配合物的前驱体反应,可生成新型富金属材料,在含能材料、热传导材料和超导材料等方面具有广阔的应用前景。

References

[1]  毕研刚, 邱少君, 赵凤起, 等.纳米铝簇配合物研究进展[J].火炸药学报, 2012,35(6): 1-6.BI Yan-gang, QIU Shao-jun, ZHAO Feng-qi, et al.Progress of research on nano-aluminum cluster complexes[J].Chinese Journal of Explosives & Propellants, 2012,35(6): 1-6.
[2]  Dohmeier C, Loos D, Schnckel H.Aluminum (I) and gallium (I) compounds: Syntheses, structures, and reactions[J].Angewandte Chemie International Edition in English, 1996,35(2): 129-149.
[3]  Tacke M, Kreienkamp H, Plaggenborg L, et al.GaCl: Ein roter, metastabiler Festkrper[J].Zeitschrift für Anorganische Und Allgemeine Chemie, 1991,604(1): 35-38.
[4]  Schmidbaur H.Arene complexes of monovalent gallium, indium, and thallium[J].Angewandte Chemie,1985,97(11): 893-904.
[5]  Massey A G.The Subhalides of Boron[J].Advances in Inorganic Chemistry, 1983,26: 1-54.
[6]  Klemm W, Voss E, Geiersberger K.Einwertige Aluminiumverbindungen III): Niedere Halogenide des Aluminiums[J].Zeitschrift für Anorganische Chemie, 1948,256(1-3): 15-24.
[7]  Schnckel, H.Infrared absorption of aluminum chloride and aluminum bromide in solid noble gases[J].Zeitschrift Fuer Naturforschung, 1976,31B(9), 1291-1292.
[8]  Tacke M, Schnckel H.Metastable aluminum chloride, AlCl, as a solid and in solution[J].Inorganic Chemistry, 1989,28(14): 2895-2896.
[9]  Uhl W.Tetrakis [bis (trimethylsilyl) methyl] dialan (4), eine verbindung mit Aluminium-Aluminium-Bindung[J].Zeitschrift für Naturforschung.B, A Journal of Chemical Sciences, 1988,43(9): 1113-1118.
[10]  Uhl W, Organometallic compounds with aluminum-aluminum, gallium-gallium, and indium-indium bonds[J].Angewandte Chemie.1993,105(10): 1449-1461.
[11]  Holtrichter-Rβmann T, Rsener C, Hellmann J, et al.Generation of weakly bound Al—N Lewis pairs by hydroalumination of ynamines and the activation of small molecules: phenylethyne and dicyclohexylcarbodiimide[J].Organometallics, 2012,31(8): 3272-3283.
[12]  Uhl W, Hagemeier E, Layh M, et al.From tert-Butylhydrazine adducts of AlR3(R=Me, CMe3) to oligonuclear AlN cage compounds-evidence for a hydrazine twist across an Al3 triangle[J].European Journal of Inorganic Chemistry, 2011,2011(11): 1733-1743.
[13]  Uhl W, Molter J, Neumüller B.Synthesis of aluminum hydrazides by hydroalumination of 2,3-diazabutadienes—formation of an Al4(N2)3 cage compound and an Al3(N2)3 macrocyclic ligand[J].Chemistry-A European Journal, 2001,7(7): 1510-1515.
[14]  邹清, 杜文亮, 马鸿雁.Al4(iPrNNiPr)3簇化合物的理论研究[J].四川大学学报, 2003,40(5): 921-925.ZOU Qing, DU Wen-liang, MA Hong-yan.Theoretical studies of Al4(iPrNNiPr)3 cage compounds[J].Journal of Sichuan University, 2003,40(5): 921-925.
[15]  许小红, 金志浩, 王永兰.氮铝簇合物的结构与稳定性[J].西安交通大学学报, 2001,35(2): 183-186.XU Xiao-hong, JIN Zhi-hao, Wang Yong-lan.Structure and stability of aluminum nitride clusters[J].Journal of Xi′an Jiaotong University.2001,35(2): 183-186.
[16]  马登学.硼(铝)的叠氮簇合物结构和性质的理论研究[D].南京: 南京理工大学, 2010.MA Deng-xue.Theoretical study on the structures and properties for the azide-clusters of boron and aluminium[D].Nanjing: Nanjing University of Science & Technology, 2010.
[17]  陈秀敏, 杨斌, 陶东平, 等.AlCl 歧化反应分解法制备金属铝过程中 [AlCl]n 的形成机理[J].物理化学学报, 2010,26(2): 415-421.CHEN Xiu-min, YANG Bing, TAO Dong-ping, et al.Formation mechanism of [AlCl]n during production of aluminum by AlCl disproportionation[J].Acta Physico-Chimica Sinica, 2010,26(2): 415-421.
[18]  卢凤仙.低价态铝簇化合物的合成探索及膦杂吡唑铝配合物的合成与表征[D].山西: 山西师范大学, 2013.LU Feng-xian.Exploration of low-valent aluminum cluster and synthesis and characterization of diazaphospholide aluminum complexes[D].Shanxi: Shanxi Normal University, 2013.
[19]  Li X, Cheng X, Song H, et al.Synthesis of HC[(CBut)(NAr)]2Al(Ar=2,6-Pri2C6H3) and its reaction with isocyanides, a bulky azide, and H2O[J].Organometallics, 2007,26(4): 1039-1043.
[20]  Li X, Song H, Cui C.Azaphosphaallyl anion lithium [ArNC(But)PAr]-Li+(THF)4 and its monomeric potassium and thallium complexes (Ar= 2,6-iPr2C6H3)[J].Dalton Transactions, 2009 (44): 9728-9730.
[21]  张坤.新颖有机铝、有机硼化合物的制备及其反应性质研究[D].天津: 南开大学, 2010.ZHANG Kun.Synthesis and reactivity of the novel organoaluminum and organoboron compounds[D].Tianjin: Nankai University, 2010.
[22]  李晓斐.新型一价铝、一价铊卡宾类似体及铝杂环丙烯化合物的合成及性质研究[D].天津: 南开大学, 2013.LI Xiao-fei.Synthesis and reactivity of the novel aluminum, thallium analogues of carbenes and aluminacyclopropene complexes[D].Tianjin: Nankai University, 2013.
[23]  Dohmeier C, Robl C, Tacke M, et al.The tetrameric aluminum (I) compound [{Al (η5-C5Me5)}4][J].Angewandte Chemie International Edition in English, 1991,30(5): 564-565.
[24]  Schno ckel H.Structures and properties of metalloid Al and Ga clusters open our eyes to the diversity and complexity of fundamental chemical and physical processes during formation and dissolution of metals[J].Chemical Reviews, 2010,110(7): 4125-4163.
[25]  Neu A, Mennekes T, Paetzold P, et al.Novel tetraalkyltetraboranes of the type B4R4, B4H2R4 and B4H4R4[J].Inorganica Chimica Acta, 1999,289(1): 58-69.
[26]  Gauss J, Schneider U, Ahlrichs R, et al.27Al NMR spectroscopic investigation of aluminum (I) compounds: ab initio calculations and experiment[J].Journal of the American Chemical Society, 1993,115(6): 2402-2408.
[27]  Koch K, Burgert R, Stsser G, et al.Understanding of the structure, bonding, formation and decomposition of metalloid aluminum clusters--a Fourier transform ion cyclotron resonance study of solid AlCp*[J].European Journal of Mass Spectrometry (Chichester, England), 2005,11(5): 469.
[28]  Wolinski K, Hinton J F, Pulay P.Efficient implementation of the gauge-independent atomic orbital method for NMR chemical shift calculations[J].Journal of the American Chemical Society, 1990,112(23): 8251-8260.
[29]  Khnlein H, Stsser G, Baum E, et al.A metalloid Al14 cluster with the structure of a “nano-wheel”[J].Angewandte Chemie International Edition, 2000,39(4): 799-801.
[30]  Wehmschulte R J, Ruhlandt-Senge K, et al.Reduction of a tetraaryldialane to generate aluminum-aluminum.pi.-bonding[J].Inorganic Chemistry, 1993,32(14): 2983-2984.
[31]  Roesky H W.The renaissance of aluminum chemistry[J].Inorganic Chemistry, 2004,43(23): 7284-7293.
[32]  Huermann U, Lidin S, Simak S I, et al.The structure of α-gallium and its relationship to deltahedral clusters[J].Chemistry-A European Journal, 1997,3(6): 904-911.
[33]  Jones R O.Simulated annealing study of neutral and charged clusters: Al and Ga[J].The Journal of Chemical Physics, 1993,99: 1194.
[34]  Akola J, Hkkinen H, Manninen M.Ionization potential of aluminum clusters[J].Physical Review B, 1998,58(7): 3601.
[35]  Ahlrichs Reinhart,Elliott Simon D.Clusters of aluminum, a density functional study[J].Physical Chemistry Chemical Physics,1999,1(1):13-21.
[36]  Khanna S N, Jena P.Assembling crystals from clusters[J].Physical Review Letters, 1993,71(1): 208-208.
[37]  Gong X G, Kumar V.Enhanced stability of magic clusters: A case study of icosahedral Al12 X, X= B, Al, Ga, C, Si, Ge, Ti, As[J].Physical Review Letters, 1993,70(14): 2078.
[38]  Leuchtner R E, Harms A C, Castleman Jr A W.Aluminum cluster reactions[J].The Journal of Chemical Physics, 1991,94: 1093.
[39]  Schriver K E, Persson J L, Honea E C, et al.Electronic shell structure of group-IIIA metal atomic clusters[J].Physical Review Letters, 1990,64(21): 2539.
[40]  de Heer W A, Milani P, Chtelain A.Nonjellium-to-jellium transition in aluminum cluster polarizabilities[J].Physical Review Letters, 1989,63: 2834-2836.
[41]  Nakajima A, Hoshino K, Naganuma T, et al.Ionization potentials of aluminum–sodium bimetallic clusters (AlNa)[J].The Journal of Chemical Physics, 1991,95: 7061.
[42]  Rao B K, Jena P.Evolution of the electronic structure and properties of neutral and charged aluminum clusters: A comprehensive analysis[J].The Journal of Chemical Physics, 1999,111: 1890.
[43]  King F L, Ross M M.Abundance distributions and dissociations of sputtered aluminum, gallium, and indium cluster ions[J].Chemical Physics Letters, 1989,164(2): 131-136.
[44]  Fuke K, Nonose S, Kikuchi N, et al.Reaction of aluminum clusters, Aln(n=7~24), with oxygen and ammonia[J].Chemical Physics Letters, 1988,147(5): 479-483.
[45]  Jarrold M F, Bower J E.Chemisorption on the microsurface of metal clusters: activation barriers and chemical reactions for carbon monoxide, nitrogen, oxygen, and methane on aluminum cluster[J].Journal of the American Chemical Society, 1988,110(20): 6706-6716.
[46]  Kaya K, Fuke K, Nonose S, et al.Reaction of Aln clusters with oxygen and ammonia[M]∥Small Particles and Inorganic Clusters.Springer Berlin Heidelberg, 1989: 571-573.
[47]  Burgert R, Schnckel H, Grubisic A, et al.Spin conservation accounts for aluminum cluster anion reactivity pattern with O2[J].Science, 2008,319(5862): 438-442.
[48]  Burgert R, Schnckel H, Olzmann M, et al.The Chlorination of the [Al13]- Cluster and the Stepwise Formation of Its Intermediate Products,[Al11]-,[Al9]-, and [Al7]-: A Model Reaction for the Oxidation of Metals[J].Angewandte Chemie International Edition, 2006,45(9): 1476-1479.
[49]  Olzmann M, Burgert R, Schnckel H.On the kinetics of the Al+ Cl reaction: Cluster degradation in consecutive steps[J].The Journal of Chemical Physics, 2009,131: 174304.
[50]  Olzmann M, Troe J.Rapid approximate calculation of numbers of quantum states W (E, J) in the phase space theory of unimolecular bond fission reactions[J].Berichte der Bunsengesellschaft für Physikalische Chemie, 1992,96(10): 1327-1332.
[51]  Gauss J.Calculation of NMR chemical shifts at second-order many-body perturbation theory using gauge-including atomic orbitals[J].Chemical Physics Letters, 1992,191(6): 614-620.
[52]  Wrackmeyer B, Contreras R.199 Hg NMR Parameters[J].Annual Reports on NMR Spectroscopy, 1992,24: 267-329.
[53]  Purath A, Dohmeier C, Ecker A, et al.Synthesis and crystal structure of the tetraaluminatetrahedrane Al4[Si(t-Bu)3]4, the second Al4R4 compound[J].Organometallics, 1998,17(9): 1894-1896.
[54]  Vollet J, Hartig J R, Schnckel H.Al50C120H180: A pseudofullerene shell of 60 carbon atoms and 60 methyl groups protecting a cluster core of 50 aluminum atoms[J].Angewandte Chemie International Edition, 2004,43(24): 3186-3189.
[55]  Clayborne P A, Lopez-Acevedo O, Whetten R L, et al.The Al50Cp*12 cluster-A 138-electron closed shell (L=6) superatom[J].European Journal of Inorganic Chemistry, 2011(17): 2649-2652.
[56]  Bono D, Hartig J, Huber M, et al.27Al NMR Study of the Metal Cluster Compound Al50C120H180[J].Journal of Cluster Science, 2007,18(1): 319-331.
[57]  Schnckel H.Formation, structure and bonding of metalloid Al and Ga clusters.A challenge for chemical efforts in nanosciences[J].Dalton Transactions, 2008 (33): 4344-4362.
[58]  Burgert R, Schnckel H.Monitoring the dissolution process of metals in the gas phase: reactions of nanoscale Al and Ga metal atom clusters and their relationship to similar metalloid clusters[J].Chemical Communications, 2008 (18): 2075-2089.
[59]  Binnewies M, Milke E.References[M].Wiley-VCH Verlag GmbH, 2002.
[60]  Vollet J, Burgert R, Schnckel H.Al20Cp*8X10 (X=Cl, Br): Snapshots of the formation of metalloid clusters from polyhedral AlnXm molecules[J].Angewandte Chemie International Edition, 2005,44(42): 6956-6960.
[61]  Huber M, Schnckel H.Al4(C5Me4H)4: Structure, reactivity and bonding[J].Inorganica Chimica Acta, 2008,361(2): 457-461.
[62]  Purath A, Dohmeier C, Ecker A, et al.Synthesis and structure of a neutral SiAl14 cluster[J].Journal of the American Chemical Society, 2000,122(29): 6955-6959.
[63]  WeiK, Schnckel H.FT/ICR–mass spectrometry in nanotechnology: the investigation of metalloid clusters[J].Analytical and Bioanalytical Chemistry, 2003,377(7-8): 1098-1101.
[64]  Li X, Grubisic A, Stokes S T, et al.Unexpected stability of Al4H6: a borane analog[J].Science, 2007,315(5810): 356-358.
[65]  Grubisic A, Li X, Stokes S T, et al.Closo-alanes (Al4H4, AlnHn+ 2, 4≤n≤ 8): A new chapter in aluminum hydride chemistry[J].Journal of the American Chemical Society, 2007,129(18): 5969-5975.
[66]  Li X, Grubisic A, Bowen K H, et al.Communications: Chain and double-ring polymeric structures: Observation of AlnH-3n+1 (n=4-8) and Al4H14[J].The Journal of chemical physics, 2010,132: 241103.
[67]  Xiang H, Kang J, Wei S H, et al.Shape control of Al nanoclusters by ligand size[J].Journal of the American Chemical Society, 2009,131(24): 8522-8526.
[68]  Wiberg N, Blank T, Nth H, et al.Dodecaindane (tBu3Si)8In12—A compound with an In12 deltapolyhedron framework[J].Angewandte Chemie International Edition, 1999,38(6): 839-841.
[69]  Khnlein H, Purath A, Klemp C, et al.Synthesis and characterization of an Al3- 69cluster with 51 naked Al atoms: analogies and differences to the previously characterized Al2-77 cluster[J].Inorganic Chemistry, 2001,40(19): 4830-4838.
[70]  Gong X G, Sun D Y, Wang X Q.Atomic and electronic shells of Al77[J].Physical Review B, 2000,62(23): 15413.
[71]  Schnckel H, Khnlein H.Synthesis and structure of metalloid aluminum clusters—intermediates on the way to the elements[J].Polyhedron, 2002,21(5): 489-501.
[72]  Uhl W, Hiller W, Layh M, et al.[Ga4{C(SiMe3)3}4] with a Tetrahedral Ga4 Skeleton[J].Angewandte Chemie International Edition in English, 1992,31(10): 1364-1366.
[73]  Beachley Jr O T, Blom R, Churchill M R, et al.indium (I) and-indium (III) compounds: syntheses, reactivities, and x-ray diffraction and electron diffraction studies of In (C5Me5)[J].Organometallics, 1989,8: 346-356.
[74]  Uhl W, Keimling S U, Klinkhammer K W, et al.TlI[C(SiMe3)3]—an alkylthallium (I) compound with a distorted tetrahedron of Tl atoms in the solid state[J].Angewandte Chemie International Edition in English, 1997,36(1-2): 64-65.
[75]  Mocker M, Robl C, Schnckel H.Donor-stabilized aluminum (I) bromide[J].Angewandte Chemie International Edition in English, 1994,33(17): 1754-1755.
[76]  Klemp C, Koeppe R, Weckert E, et al.Al22Br20·12THF: The first polyhedral aluminum subhalide—a step on the path to a new modification of aluminum[J].Angewandte Chemie International Edition, 1999,38(12): 1739-1743.
[77]  Klemp C, Bruns M, Gauss J, et al, Schnckel H.Al22Cl20·12L (L=THF, THP): The first polyhedral aluminum chlorides[J].Journal of the American Chemical Society, 2001,123(37): 9099-9106.
[78]  Schnockel H, Klemp C.Molecular aluminium and gallium subhalides[J].Inorganic Chemistry Highlights, 2002 (1): 1966.
[79]  Henke P, Huber M, Steiner J, et al.Al4(PtBu2)6-a derivative of Al4H6-and other Al4 Species: a challenge for bonding interpretation between zintl ions and metalloid clusters[J].Journal of the American Chemical Society, 2009,131(15): 5698-5704.
[80]  Wiberg N, Amelunxen K, Blank T, et al.Tetrasupersilyldialuminum [(t-Bu)3Si]2Al-Al[Si (t-Bu)3]2: The Dialane (4) with the Longest Al-Al Bond to Date, §[J].Organometallics, 1998,17(24): 5431-5433.
[81]  Hardman N J, Wright R J, Phillips A D, et al.Synthesis and Characterization of the Neutral “Digallene” Ar′GaGaAr′ and Its Reduction to Na2Ar′GaGaAr′(Ar′=2,6-Dipp2C6H3, Dipp= 2,6-iPr2C6H3)[J].Angewandte Chemie, 2002,114(15): 2966-2968.
[82]  Pankewitz T, Klopper W, Henke P, et al.Isomeric Al2R4, Mg2R2 Species and Oligomerisation Products: Investigation of Al—Al and Mg—Mg σ Bonding[J].European Journal of Inorganic Chemistry, 2008,2008(31): 4879-4890.
[83]  Haaland A, Martinsen K G, Shlykov S A, et al.Molecular structure of monomeric (pentamethylcyclopentadienyl) aluminum (I) by gas-phase electron diffraction[J].Organometallics, 1995,14(6): 3116-3119.
[84]  Wiberg N, Blank T, Kaim W, et al.Compounds of silicon and homologues, 134-Supersilyl compounds of boron and homologues, 10-Tri (supersilyl) dialanyl (tBu3Si)3Al2′ and tetra (supersilyl) cyclotrialanyl (tBu3Si)4Al3′-New stable radicals of a group 13 element from thermolysis of (tBu3Si)4Al2′[J].European Journal of Inorganic Chemistry, 2000 (7): 1475-1481.
[85]  Linti G, Schnckel H, Uhl W, Wiberg N.Clusters of the heavier group 13 elements[J].Molecular Clusters of the Main Group Elements, 2004: 126-168.
[86]  Gemel C, Steinke T, Cokoja M, et al.Transition metal chemistry of low valent group 13 organyls[J].European Journal of Inorganic Chemistry, 2004,2004(21): 4161-4176.
[87]  Kuznetsov A E, Birch K A, Boldyrev A I, et al.All-metal antiaromatic molecule: rectangular Al44- in the Li3Al4- anion[J].Science, 2003,300(5619): 622-625.
[88]  Kuznetsov A E, Corbett J D, Wang L S, et al.Aromatic mercury clusters in ancient amalgams[J].Angewandte Chemie, 2001,113(18): 3473-3476.

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