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含能材料  2014 

3,5-二硝氨基-1,2,4-三唑肼盐的合成及性能

DOI: 10.3969/j.issn.1006-9941.2014.04.027

Keywords: 有机化学,3,5-二硝氨基-1,2,4-三唑肼盐,合成,性能

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Abstract:

以硝基胍和甲醛为原料,经缩合反应、硝化反应和肼解反应得到总收率为63.69%的3,5-二硝氨基-1,2,4-三唑肼盐(HDNAT),并对其进行了表征了结构。测试了HDNAT的部分物化、爆轰性能。结果为:密度1.89g·cm-3,熔点194~196℃,摩擦感度92%,撞击感度100%,H5026.8cm,爆速9000m·s-1(ρ=1.80g·cm-3).采用VLMmethod计算其爆压为36.0GPa。

References

[1]  LI Guan-qiong, LI Yu-chuan, MA Qiao-li, et al.Research progress in synthesis of nitrogen-rich zole-ring compounds by cycloaddition reaction[J].Chinese Journal of Organic Chemistry, 2010,30(10):1431-1440.
[2]  LIU Xiao-jian, ZHANG Hui-juan, LIN Qiu-han, et al.Progress of study on the synthesis of azole energetic ionic compounds[J].Chinese Journal of Explosives & Propellant, 2010,33(1): 6-10.
[3]  Lee K, Storm C, Hiskey M, et al.An improved synthesis of 5-amino-3-nitro-1H-1,2,4-triazole(ANTA), a useful intermediate for the preparation of insensitive high explosives [J].Journal of Energetic Materials, 1991,9(5): 415-428.
[4]  WANG Xi-jie, JIA Si-yuan, WANG Bo-zhou, et al.Synthesis improvement of 5-amino-3-nitro-1,2,4- triazole (ANTA)[J].Chinese Journal of Energetic Materials(Hanneng Cailiao), 2006,14(6): 439-440.
[5]  ZHU Zhao-yang, CAO Yi-lin, SUN Zhong-xiang, et al.Investigation on synthesis and properties of 5,5′-dinitro-3,3′-azo-1-hydro-1,2,4-triazole(DNAT)[J].Journal of Solid Rocket Technology, 2008,31(5): 501-503.
[6]  XIA Yun-xia, WANG Ping, SUN Jie, et al.Synthesis and properties of 4-amino-1,2,4-triazole picrate[J].Fine Chemicals, 2008,25(5): 445-448.
[7]  ZHANG Hai-hao, JIA Si-yuan, WANG Bo-zhou, et al.Synthesis and characterization of 3-amino(nitro)- 5-nitro-1,2,4-triazole derivatives[J].Chinese Journal of Energetic Materials(Hanneng Cailiao), 2010,18(1): 29-33.
[8]  HE Yun, FAN Gui-juan, ZHANG Guang-quan, et al.Review on synthesis and reactivity of 5-amino-3- nitro-1,2,4-trizole[J].Chinese Journal of Energetic Materials(Hanneng Cailiao), 2012,20(6): 715-720.
[9]  ZHOU Qun, WANG Bo-zhou, JIA Si-yuan.New synthetic of 1-methyl-3-amino-5-nitro- 1,2,4-triazole[J].Chinese Journal of Energetic Materials(Hanneng Cailiao), 2012,20(1): 26-29.
[10]  LI Lei, CHI Yu, ZHANG Yong, et al.Synthesis, characterization and crystal structure of 4,4′-bis-1,2,4-trizole[J].Chinese Journal of Energetic Materials(Hanneng Cailiao), 2013,21(4): 429-433.
[11]  XU Hai-feng, WANG Juan, LI Yong-qiang, et al.Synthesis of 2,4,6-trinitro-3,5-diamino-N-(1,2,4-trizole-4)-aniline[J].Chinese Journal of Energetic Materials(Hanneng Cailiao), 2013,21(6): 721-725.
[12]  LUO Yi-fen, CHEN Xiao-fang, WANG Bo-zhou, et al.Synthesis, thermal performance and quantum chemistry study on 4-nitro-2-(1-nitro-1,2,4-triazole-3-yl)-1,2,3-triazole(DNDTz)[J].Chinese Journal of Explosives & Propellant, 2013,36(4): 13-17.
[13]  HUO Huan, WANG Bo-zhou, ZHOU Cheng, et al.Synthesis and characterization of 4-amino-5-nitro- 1,2,3 -triazole[J].Chinese Journal of Energetic Materials(Hanneng Cailiao), 2008,16(1): 49-52.
[14]  WANG Bo-zhou, LI Ji-zhen, HUO Huan, et al.Synthesis, characterization and thermal behaviors of 4-amino-5-nitro-1,2,3-triazole (ANTZ) and its derivatives[J].Chin J Chem, 2010,28: 781-784.
[15]  SHI Hong-gang, LI Sheng-hua, LI Yu-chuan, et al.Synthesis of l-amino-1,2,3-triazole[J].Chinese Journal of Energetic Materials(Hanneng Cailiao), 2008,16(6): 676-678.
[16]  LI LIN, YE Zhi-wen, Lü Chun-xu.Synthesis and characterization of 1-amino-3-methyl- 1,2,3-triazolium nitrate[J].Chinese Journal of Energetic Materials(Hanneng Cailiao), 2012,20(1): 9-12.
[17]  WU Xiong, LONG Xin-Ping, HE Bi, et al.The VLW equation of state for detonation products[J].Science in China, 2008,38(12): 1129-1131.

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