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含能材料  2014 

双肼基均四嗪十氢十硼酸盐的合成

DOI: 10.3969/j.issn.1006-9941.2014.03.029

Keywords: 有机化学,3,6-双肼基-1,2,4,5-四嗪,双肼基均四嗪十氢十硼酸盐

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Abstract:

以3,6-双(3,5-二甲基吡唑)-1,2,4,5-四嗪为原料通过肼基取代反应合成了3,6-双肼基-1,2,4,5-四嗪,以十氢十硼酸双四乙基铵盐为原料通过离子交换法制备了十氢十硼酸,再经过成盐反应合成了双肼基均四嗪十氢十硼酸盐化合物,产率为80%。通过IR、1HNMR、元素分析等方法对产物的结构进行了表征。采用氧弹燃烧法,测试其燃烧热值为37.5kJ·g-1。

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