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灰化法磷测定中不同灰化助剂的效果比较:以焦磷酸钠作为磷标样

, PP. 58-64

Keywords: 磷测定,灰化法,Na4P2O7,灰化助剂

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Abstract:

对Na4P2O7加入不同灰化助剂经不同温度(200~550℃)灼烧后磷的回收率进行了研究.所研究的灰化助剂除文献中已深入研究过的MgSO4和Mg(NO3)2外,还对MgCl2等10余种盐试剂进行了实验.结果表明,除Mg(NO3)2外,MgCl2,MgAc2,CaCl2,Ca(NO3)2等均能使Na4P2O7灰化后的磷完全回收(灼烧温度不低于450℃),而加入MgSO4在任何灼烧温度下磷的回收率均低于80%,效果不佳.因此,在利用目前已被广泛应用的由Solrzno和sharp所提出的方法去分析海水中颗粒磷和总磷或有机体中的磷时,应当用MgCl2(或MgAc2)作为灰化助剂来取代MgSO4.

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