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湖泊科学  2014 

淡水可溶性硅的4种测定方法比较

DOI: 10.18307/2014.0311

Keywords: 可溶性硅,比色法,1,2,4氨基萘酚磺酸还原硅钼蓝法,玻璃容器,磷酸根离子干扰

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Abstract:

通过加标回收和野外水样测定,对用于淡水可溶性硅测定的4种比色法进行比较,同时研究了实验过程中玻璃容器对4种方法测定结果的影响以及磷酸根离子对显色的干扰.结果表明:1,2,4氨基萘酚磺酸还原硅钼蓝法的灵敏度和准确性高,适合常规水样中可溶性硅的测定,最适检测浓度范围为0.05~20mg/L;米吐尔还原硅钼蓝法和抗坏血酸还原硅钼蓝法灵敏度高但准确性低;硅钼黄法操作简单但灵敏度低.测定过程所使用的玻璃容器对4种方法的测定结果没有影响,磷酸根离子的干扰能被消除.

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