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二维铜配合物聚合物[Cu(MDNS)2]n的合成与表征

DOI: 10.11830/ISSN.1000-5013.2013.04.0404

Keywords: 3, 5-二硝基水杨酸甲酯, Cu(Ⅱ), 配位聚合物, 晶体结构, 溶液法

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Abstract:

采用溶液法合成铜的配位聚合物[Cu(MDNS)2]n(HDNS=3,5-二硝基水杨酸甲酯).研究表明,该化合物属单斜晶系,空间群为P21/c,分子式为C8H6N2O7.其晶胞参数:a=1.100 2(4)nm, b=1.123 3(4)nm,c=0.814 6(3)nm, β=107.970(6)°, V=0.957 7(6)nm3, Z=2,μ=1.233 mm-1, Dc=1.893 g?cm-3, F(000)=555, R=0.034 6,Rw=0.102 6.在标题化合物中,Cu2+离子由2个3,5-二硝基水杨酸甲酯的2个羰基氧原子和2个酚氧原子,以及另2个3,5-二硝基水杨酸甲酯的2个硝基氧原子配位,共同形成CuO6畸变的八面体配位构型.每一个3,5-二硝基水杨酸甲酯都同时桥联2个Cu2+离子,将化合物联结成二维网状结构的配位聚合物.

References

[1]  LAMA P,SA(~overN)UDO E C,BHARADWAJ P K.Coordination polymers of Mn2+ and Dy3+ ions built with a bent tricarboxylate: Metamagnetic and weak anti-ferromagnetic behavior[J].Dalton Trans,2012,41(10):2979-2985.
[2]  YANG Peng,HE Xiang,LI Ming-xing,et al.The first homochiral coordination polymer with temperature-independent piezoelectric and dielectric properties[J].J Mater Chem,2012,22(6):2398-2400.
[3]  HASHEMI L,MORSALI A.Microwave assisted synthesis of a new lead(Ⅱ)porous three-dimensional coordination polymer: Study of nanostructured size effect on high iodide adsorption affinity[J].Cryst Eng Comm,2012,14(3):779-781.
[4]  WANG Kuai-bing, YIN Yu-xin, WANG Zhi-lin, et al. Facile synthesis of zinc(Ⅱ)-carboxylate coordination polymer particles and their luminescent, biocompatible and antibacterial properties[J]. Cryst Eng Comm,2011,13(20):6231-6236.
[5]  ZHANG Jian-yong,JING Xue-hui,MA Yu,et al.Interpenetration,self-catenation, and new topology in metal-organic frameworks of cobalt with mixed organic linkers[J].Cryst Growth Des,2011,11(9):3681-3685.
[6]    1/2 spin ground state[J].Inorg Chem Commun,2011,14(6):925-928.
[7]  MENG Yan.Poly[(l-2-hydroxy-3,5-dinitrobenzoato)-rubidium][J].Acta Cryst,2011,E67(4):454.
[8]  HU Man-cheng, GENG Chun-yu, LI Shu-ni, et al.Syntheses and crystal structures of three cesium salts: Cesium 5-sulfosalicylate, cesium 3,5-dinitrosalicylate and cesium 2,4-dinitrophenoxide monohydrate[J].J Organomet Chem,2005,690(13):3118-3124.
[9]  YANG En-cui,LIU Zhong-yi,ZHAO Xiao-jun,et al.Ligand-deprotonation induced structural diversity in a ternary Cu-triazoletetracarboxylate self-assembly system: Synthesis,crystal structures, and magnetic behavior[J].Cryt Eng Comm,2011,13(17):5401-5408.
[10]  WANG Feng-qin,LU Fan-li,WEI Bin,et al.Poly[[di-μ-aqua-tetraaquadi-μ-hydroxide-bis(μ3-3-nitrophthalato)-tricopper(Ⅱ)] dihydrate][J].Acta Cryst,2009,C65(1):m42-m44.
[11]  LIU Zhong-yi,CHU Jing,DING Bo,et al.A novel CuⅡ5 cluster-based 3D magnetic framework with an overall S=
[12]  SONG Wen-dong,GUO Xian-xia,ZHANG Chao-hua.Poly[aqua(μ3-3,5-dinitrosalicylato)calcium(Ⅱ)][J].Acta Cryst,2007,E63(2):m399-m401.
[13]  SONG Wen-dong, FAN Run-zhen, GU Chang-sheng, et al. Poly[[μ2-aqua-aqua(μ3-3,5-dinitro-salicylato)barium(Ⅱ)] monohydrate][J].Acta Cryst,2008,E64(4):m551.
[14]  MA Shu-lin,REN Shi,YANG Yun.New binuclear complexes with mixed ligands and μ2-phenol oxygen bridges:Synthesis crystal structures and magnetism[J].J Inorg Organomet Polym,2010,20(1):104-109.
[15]  ERXLEGEN A.Copper coordination to the aldehyde and hemiacetal form of 4-bromo-2-[(2-diethylaminoethyl)ethylaminomethyl]-6-formylphenol[J].Inorg Chim Acta,2009,362(3):839-844.
[16]  CHEN Li-hua,ZHAO Gan-qing,WANG Xiang.(2-acetylphenolato)(2,2-bipyridine)-nitrato copper(Ⅱ)[J].Acta Cryst,2009,E65(11):m1427.
[17]  GERAGHTY M,SHERIDAN V,MCCANN M.Synthesis and anti-candida activity of copper(Ⅱ)and manganese(Ⅱ)carboxylate complexes[J].Polyhedron,1999,18(22):2931-2939.
[18]  QU Yang,PENG Jian-jun.Tetraamminebis(4-nitrobenzoato-κO)copper(Ⅱ)[J].Acta Cryst,2006,E62(5):m952-m953.
[19]  LIU Zhi-qiang,LI Yan-tuan,WU Zhi-yong,et al.A two-dimensional copper(Ⅱ)polymer with bridging μ-trans-oxamidate and μ2-picrate ligands: Synthesis, crystal structure and DNA binding studies[J].Inorg Chim Acta,2008,361(1):226-232.

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