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材料工程  2013 

改性海绵铁除氧影响因素与机理研究

DOI: 10.3969/j.issn.1001-4381.2013.10.013

Keywords: 改性海绵铁,溶解氧,表征,反应动力学,速率常数

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Abstract:

采用反应动力学分析、表面分析、扫描电镜(SEM)和X射线能谱仪(EDS)研究了诸外因对改性海绵铁除氧行为的影响及除氧相关机理。结果表明改性海绵铁表面铜含量增加对除氧能力的促进作用大于比表面积减小使除氧能力降低的影响。改性海绵铁除氧过程为反应控制过程并符合一级反应动力学方程。另外,诸外因中溶液初始pH值和初始电导率对除氧速率常数的影响规律是先增后减。增加改性海绵铁投加量和溶液温度对除氧速率常数的提高具有促进作用,但继续增加改性海绵铁的投加量并不能无限提高除氧速率常数,速率常数存在极限值为0.3663min-1。

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