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材料工程  2008 

多壁碳纳米管的超声处理对PtRu/MWCNTs电催化性能的影响

Keywords: 多壁碳纳米管,超声,官能团化,直接甲醇燃料电池

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Abstract:

多壁碳纳米管的表面官能团化对其在催化领域的应用有重要意义。在硫酸和硝酸混合液中超声处理多壁碳纳米管,在使其纯化的同时,纳米管的长度变短,端口被打开,并在碳纳米管表面和端口处修饰上大量的含氧官能团,有利于催化剂活性组分在碳纳米管表面均匀沉积。利用透射电镜,红外光谱和拉曼光谱表征了碳纳米管及其催化剂的表观织构。通过交流阻抗谱对催化剂进行电化学性能测试,并发现经过超声处理的碳纳米管负载的PtRu双金属催化剂对甲醇有较好的电催化活性。

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