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材料工程  2008 

液相掺杂PTC瓷粉的制备及其电性能研究

, PP. 142-144

Keywords: 低温固态反应,纳米钛酸钡瓷粉,烧结条件

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Abstract:

以TiCl4为钛源,通过低温固态反应合成了一系列掺杂Ba0.93-xYxSr0.07MnyTi1-yO3纳米固溶体粉末。经XRD物相分析证明,产品为立方晶系的完全互溶取代固溶体。TEM电镜形貌分析,粒子分布较均匀,基本呈规则球形,粒径大约70nm。通过制陶实验,研究了材料的PTC效应,当施主Y和受主Mn的掺杂量分别为1%和0.04%(摩尔分数)时,得到了室温电阻37.09Ω左右,升阻比达到2.957×105,电阻温度系数α为23.36%的性质优良的PTC陶瓷材料。

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