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材料工程  2014 

外加应变对航空有机涂层防护性能的影响

DOI: 10.11868/j.issn.1001-4381.2014.05.001, PP. 1-6

Keywords: 预应变,有机涂层,防护性能,户外暴晒,电化学阻抗谱

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Abstract:

设计了一种板条形涂层试样预应变施加方法,并通过原始标定和显微观察的方法定量确定有机涂层应变量,以此模拟航空涂层防护体系在服役过程中遭受的应变。将施加了不同应变的板条形有机涂层试样进行户外暴晒,样品所处条件与实际服役中自然环境因素-力学因素耦合作用的情况更为接近,从而可以得到更为准确的防护性能评价结果。结果表明无外加应变状态的锌黄丙烯酸聚氨酯涂层的阻抗模值随着在万宁自然老化时间的延长而下降,在户外暴晒36个月的过程中,涂层的阻抗模值从1.8×109Ω下降到4.7×105Ω;经过户外暴晒后,外加压应变状态和外加拉应变状态涂层试样的阻抗模值都发生下降,但外加拉应变状态涂层模值降低的幅度更大,表明外加拉应变对有机涂层防护性能影响更大。

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