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同位素  2014 

D12-孔雀石绿的合成

DOI: 10.7538/tws.2014.27.02.0077, PP. 77-81

Keywords: 同位素标记,孔雀石绿,合成,表征

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Abstract:

以CD3OD为起始原料,经甲基化、缩合、氧化等步骤合成稳定同位素标记D12-孔雀石绿。以消耗CD3OD计算,稳定同位素标记D12-孔雀石绿的总收率为50.1%。产品结构经高效液相色谱(HPLC)、质谱(MS)及核磁共振波谱(NMR)等仪器表征确定,D12-孔雀石绿色谱纯度高于99.0%,氘同位素丰度大于99.0%,结果表明,D12-孔雀石绿可作为食品安全领域检测用同位素内标试剂。

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