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一种马来酰亚胺双酚A型苯并噁嗪的合成研究

, PP. 392-397

Keywords: 苯并噁嗪,双酚A,合成,热固性,高性能聚合物

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Abstract:

以顺丁烯二酸酐、对硝基苯胺、甲醛、双酚A为原料,采用多步反应经中间产物N-(4-硝基苯基)马来酰亚胺(NPMI)、N-(4-氨基苯基)马来酰亚胺(APMI)、1,3,5-三(4-(马来酰亚胺)苯基)-1,3,5-三嗪(TMIPT)等最终合成出双(2,4-二氢-2H-3-(4-N-马来酰亚胺)苯基-1,3-苯并噁嗪)异丙烷(BMIPBI);并采用1HNMR、FT-IR、EA等方法对产物BMIPBI进行了检测,证实了所得产物为目标物BMIPBI,并对其溶解性进行了测试;所得BMIPBI为黄色疏松状固体,产品收率58.8%.

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