全部 标题 作者
关键词 摘要

OALib Journal期刊
ISSN: 2333-9721
费用:99美元

查看量下载量

相关文章

更多...

高效水-有机两相催化研究进展

, PP. 306-311

Keywords: 水-有机两相催化剂,高催化活性,重复使用性,表面活性剂,相转移剂,水溶性高分子,多功能配体

Full-Text   Cite this paper   Add to My Lib

Abstract:

水-有机两相催化体系因其绿色环保的特点受到人们的极大关注.目前,水-有机两相催化体系的发展重点是改善两相体系的传质效率、提高其催化活性.对构建高效水-有机两相催化体系的几种常用方法进行了综述,包括表面活性剂和相转移剂的使用、利用水溶性高分子负载催化剂以及新型多功能配体的使用等.探讨了这些方法的优点与缺陷,并对水-有机两相催化体系的发展提出展望.

References

[1]  Herrmann W A, Kohlpainter W. Water-soluble ligands, metal complexes, and catalysts: Synergism of homogeneous and heterogeneous catalysis[J]. Angew Chem:Int Edit,1993,32:1524-1544.
[2]  Cornils B. Exciting results from the field of homogeneous two-phase catalysis[J]. Angew Chem:Int Edit,1995,34:1575-1577.
[3]  Papadogianakis G, Sheldon R A. Catalytic conversions in water: Environmentally attractive processes employing water soluble transition metal complexes[J]. New J Chem,1996,20:175-185.
[4]  Joó F, Kathó . Recent developments in aqueous organometallic chemistry and catalysis[J]. J Mol Catal:Chem,1997,A116:3-26.
[5]  Li C J. Quasi-nature catalysis: Developing CC bond formations catalyzed by late transition metals in air and water[J]. Acc Chem Res,2002,35:533-538.
[6]  Manabe K, Kobayashi S. Catalytic asymmetric carbon-carbon bond-forming reactions in aqueous media[J]. Chem Eur J,2002,8:4094-4101.
[7]  Sinou D. Asymmetric organometallic-catalyzed reactions in aqueous media[J]. Adv Synth Catal,2002,344:221-237.
[8]  Pinault N, Bruce D W. Homogeneous catalysts based on water-soluble phosphines[J]. Coordin Chem Rev,2003,241:1-25.
[9]  RajanBabu T V, Yan Y Y, Shin S. Asymmetric catalysis in water: Prospects and problems of using hydroxyphosphines and hydroxyphosphinites as ligands[J]. Curr Org Chem,2003,7:1759-1773.
[10]  Genêt J P, Darses S, Michelet V. Organometallic catalysts in synthetic organic chemistry: From reactions in aqueous media to gold catalysis[J]. Pure Appl Chem,2008,80:831-844.
[11]  Purwanto P, Delmas H. Gas-liquid-liquid reaction engineering: Hydroformylation of 1-octene using a water soluble rhodium complex catalyst[J]. Catal Today,1995:135-140.
[12]  Jessop P G, Subramaniam B. Gas-expanded liquids[J]. Chem Rev,2007,107:2666-2694.
[13]  Robbins G P, Hallett J P, Bush D, et al. Liquid-liquid equilibria and partitioning in organic-aqueous systems[J]. Fluid Phase Equilib,2007,253:48-53.
[14]  Wang X, Fu H Y, Li X, et al. Hydroformylation of high olefin in biphasic catalytic system: Effect of electronic and steric factor of phosphine ligands[J]. Catal Commun,2004,5:739-741.
[15]  Kunna K, Müller C, Loos J, et al. Aqueous-phase hydroformylation of 1-octene: Styrene latices as phase-transfer agents[J]. Angew Chem:Int Edit,2006,45:7289-7292.
[16]  Desset S L, Cole-Hamilton D J, Foster D F. Aqueous-biphasic hydroformylation of higher alkenes promoted by alkylimidazolium salts[J]. Chem Commun,2007:1933-1935.
[17]  Kirschner D, Jaramillo M, Green T, et al. Fine tuning of sulfoalkylated cyclodextrin structures to improve their mass-transfer properties in an aqueous biphasic hydroformylation reaction[J]. J Mol Catal:Chem,2008,A286:11-20.
[18]  Bortenschlager M, Schoellhorn N, Wittmann A, et al. Chem Eur J,2007,13:520-528.
[19]  Zarka M T, Bortenschlager M, Wurst K, et al. Immobilization of a rhodium carbene complex to an amphiphilic block copolymer for hydroformylation of 1-octene under aqueous two-phase conditions[J]. Organometallics,2004,23:4817-4820.
[20]  Malmstrm T, Ersson C. Enantioselective hydrogenation in water catalysed by rhodium phosphine complexes bound to polyacrylic acid[J]. J Mol Catal:Chem,1999,A139:259-270.
[21]  Buhling A, Elgersma J W, Nkrumah S, et al. Novel amphiphilic diphosphines: Synthesis, rhodium complexes, use in hydroformylation and rhodium recycling[J]. J Chem Soc Dalton Trans,1996:2143-2154.
[22]  Ding H, Hanson B E. Reaction activity and selectivity as a function of solution ionic strength in oct-1-ene hydroformylation with sulfonated phosphines[J]. J Chem Soc Chem Commun,1994:2747-2748.
[23]  Bartik T, Bartik B, Hanson B E. Aqueous phase rhodium hydroformylation of octene-1 with trisulfonated tris (ω-phenyl) alkylphosphines and trisulfonated triphenyl phosphine. Reaction selectivity as an indication of rhodium-phosphine complex chemistry[J]. J Mol Catal,1994,88:43-56.
[24]  Leadbeater N E. Fast, easy, clean chemistry by using water as a solvent and microwave heating: the Suzuki coupling as an illustration[J]. Chem Commun,2005:2881-2902.
[25]  Chen H, Li Y, Chen J, et al. Micellar effect in high olefin hydroformylation catalyzed by water-soluble rhodium complex[J]. J Mol Catal:Chem,1999,A149:1-6.
[26]  Chen H, Li Y, Li R, et al. Highly regioselective hydroformylation of 1-dodecene catalyzed by Rh-BISBIS in aqueous two-phase system[J]. J Mol Catal:Chem,2003,A198:1-7.
[27]  Fu H, Li M, Mao H, et al. Aqueous biphasic catalytic hydroformylation of higher olefins: Promotion effect of cationic gemini and trimeric surfactants[J]. Catal Commun,2008,9:1539-1544.
[28]  Li M, Fu H, Yang M, et al. Micellar effect of cationic gemini surfactants on organic/aqueous biphasic catalytic hydroformylation of 1-dodecene[J]. J Mol Catal:Chem,2005,A235:130-136.
[29]  李敏,徐斌,陈华,等. 两相催化体系中双子表面活性剂对1-十二烯氢甲酰化反应的促进作用[J]. 高等学校化学学报,2004,4:717-720.
[30]  Miyagawa C C, Kupka J, Schumpe A. Rhodium-catalyzed hydroformylation of 1-octene in micro-emulsions and micellar media[J]. J Mol Catal:Chem,2005,A234:9-17.
[31]  Monflier E, Tilloy S, Fremy G, et al. Tetrahedron Lett,1995,36:9481-9484.
[32]  Leclercq L, Bricout H, Tilloy S, et al. J Colloid Interface Sci,2007,307:481-487.
[33]  Leclercq L, Sauthier M, Castanet Y, et al. Adv Synth Catal,2005,347:55-59.
[34]  Monflier E, Fremy G, Castanet Y, et al. Angew Chem:Int Edit,1995,34:2269-2271.
[35]  Leclercq L, Hapiot F, Tilloy S, et al. Organometallics,2005,24:2070-2075.
[36]  Reetz M T, Waldvogel S R. Angew Chem:Int Edit,1997,36:865-867.
[37]  Loch J A, Borgmann C, Crabtree R H. J Mol Catal:Chem,2001,A170:75-80.
[38]  Jiang J, Wang Y, Liu C, et al. J Mol Catal:Chem,1999,A147:131-136.
[39]  Chen R, Liu X, Jin Z. J Organomet Chem,1998,571:201-204.
[40]  Valls E, Suades J, Suades R. Organometallics,1999,18:5475-5483.
[41]  Sieber F, Wentworth P Jr, Toker J D, et al. J Org Chem,1999,64:5188-5192.
[42]  Hoen R, Leleu S, Botman P N M, et al. Org Biomol Chem,2006,4:613-615.
[43]  Bortenschlager M, Schoellhorn N, Wittmann A, et al. Chem Eur J,2007,13:520-528.
[44]  Zarka M T, Nuyken O, Weberskirch R. Chem Eur J,2003,9:3228-3234.
[45]  Borowski A F, Cole-Hamilton D J, Wilkinson G. NouV J Chim,1978,2:137-144.
[46]  Andriollo A, Carrasquel J, Mario J, et al. J Mol Catal:Chem,1997,A116:157-165.
[47]  Smith R T, Ungar R K, Sanderson L J, et al. Organometallics,1983,2:1138-1144.
[48]  Fell B, Papadogianakis G. J Mol Catal:Chem,1991,A66:143-154.
[49]  孙达旺. 植物单宁化学[M]. 北京:中国林业出版社,1992.
[50]  Galvez J M G, Riedl B, Conner A H. Holzforschung,1997,51:235-543.
[51]  Mao H, Liao X P, Shi B. Catal Commun,2011,16:210-214.
[52]  Mao H, Liao X P, Shi B. J Chem Technol Biot,2011,87:1104-1110.
[53]  石碧,狄莹. 植物多酚[M]. 北京:科学出版社,2000.
[54]  金子林,赵玉亮,王艳华. 温控配体与液/液两相催化[J]. 催化学报,2003,24:391-399.
[55]  金子林,刘宁,刘春. 温控液/液两相催化进展[J]. 化学进展,2010,22:1295-1309.
[56]  Jin Z L, Yan Y Y, Zuo H P, et al. J Prakt Chem/Chem-Ztg,1996,338:124.

Full-Text

Contact Us

service@oalib.com

QQ:3279437679

WhatsApp +8615387084133