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(Ba_(1-α)Sr_α)_(4.8)(Sm_(0.7)La_(0.3))_(8.8)Ti_(18)O_(54)陶瓷的微波介电性能

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Abstract:

采用固相合成法制备了(Ba_(1-α)Sr_α)_(4.8)(Sm_(0.7)La_(0.3))_(8.8)Ti_(18)O_(54)(α=0.1~0.5)系陶瓷,表征了该陶瓷的相组成和显微结构,测试了微波介电性能。结果表明α=0.3时,(Ba_(1-α)Sr_α)_(4.8)(Sm_(0.7)La_(0.3))_(8.8)Ti_(18)O_(54)系陶瓷为单相的新钨青铜结构固溶体。α>0.3时,相继出现了第二相BaLa_2Ti_4O_(12)和La_(0.66)TiO_(2.993)。随α的增加,(Ba_(1-α)Sr_a)_(4.8)(Sm_(0.7)La_(0.3))_(8.8)Ti_(18)O_(54)系陶瓷的相对介电常数(ε_r)先增大后有所波动,品质因数(Q_f)先增大后减小,谐振频率温度系数(τ_f)单调减小。α=0.3时,在1350℃烧结的陶瓷的微波介电性能最佳ε_r=98.77,Q_f=5184GHz,τ_f=10.9×1~(-6)/℃,优于不掺杂的BaO-Sm_2O_3-TiO_2陶瓷的。

References

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