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Mn(1–x)S:Ax/ZnS纳米晶的制备及荧光性能

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Abstract:

采用化学沉淀法合成了Mn(1–x)SAx/ZnS(AEu,Pr)纳米晶,其结构为闪锌矿结构,平均粒度约4nm。荧光光谱表明Mn(1–x)SAx/ZnS(AEu,Pr)纳米晶除了ZnS本身的缺陷发光和Mn离子的发光外,还出现了新的掺杂离子的发光峰。对应在575nm和617nm处发光峰来自于Eu3+的5D0→7F1和5D0→7F2的跃迁。另外,与纯的Mn(1–x)SAx相比,ZnS包覆Mn(1–x)SAx后,纳米晶在580nm处的发光性能明显增强。

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