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一种硅基介孔材料的制备及其对低浓度Co2+的选择性吸附

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Abstract:

以介孔硅材料MCM-41为基体,采用接枝法设计合成了三类含巯基和胺基的新型吸附材料,通过X射线衍射、Fourier变换红外光谱及N2吸附–脱附实验,对材料的结构进行了表征,探讨了改性剂APTS与MPTMS配比对结构的影响,并对材料Co2+的吸附性能进行了静态吸附实验。结果表明APTS与MPTMS的质量比为12时制备的吸附材料MA-MCM-2对低浓度Co2+具有较高的去除率,达到50%以上,好于其他两种;MA-MCM-1和MA-MCM-2等温吸附结果与Langmuir方程及Freundlich方程均能较好地拟合,其饱和吸附容量分别为0.227mmol/g和0.251mmol/g;吸附过程遵循Lagergren准二级动力学方程,Co2+在MA-MCM-1的吸附过程受液膜扩散和颗粒扩散共同作用,而MA-MCM-2和MA-MCM-3受液膜扩散作用主导。在干扰离子Ca2+和Mg2+含量达到200mg/L时,MA-MCM-2对低浓度Co2+的去除效率仍达到38%,表现出了一定的干扰能力。

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