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用于固体氧化物燃料电池的Zn掺杂BaZr0.7Pr0.1Y0.2O3–δ质子导体电解质的制备与性能

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Abstract:

采用柠檬酸–硝酸盐燃烧法制备了质子导体固体氧化物燃料电池(SOFC)电解质材料BaZr0.7Pr0.1Y0.2O3–δ(BZPY)和BaZr0.7Pr0.1Y0.16Zn0.04O3–δ(BZPYZn)。研究了Zn掺杂对材料烧结、热膨胀系数和电性能的影响;利用X射线衍射仪和扫描电子显微镜对样品物相和微观结构进行了表征。结果表明BZPYZn经1100℃煅烧5h后呈单一的钙钛矿结构。随烧结温度的升高(从1300℃到1400℃),BZPYZn陶瓷体的晶粒尺寸增大,而孔隙率减小;1350℃保温5h烧结的BZPYZn陶瓷样品的相对密度达到97.3%;500~800℃范围内,离子电导率介于10–3~10–2S/cm之间。室温至1000℃范围内,样品的热膨胀系数为9.2×10–6/K,表明其与电极材料(Ni)的热匹配性好。预示BZPYZn有望成为良好的质子传导型中温SOFC电解质材料。

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