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水泥基材料中自由氯离子浓缩的影响因素

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Abstract:

研究了NaCl浸泡液浓度、浸泡时间、养护时间、浸泡温度和压滤压力对水泥基材料孔溶液中氯离子浓缩的影响。结果表明在NaCl溶液中浸泡56d后,水泥基材料试件孔溶液中自由氯离子浓度与浸泡液的氯离子浓度有很好的线性关系。当浸泡液浓度≤0.3mol/L时,自由氯离子浓度比浸泡液的氯离子浓度至少高40%;当浸泡液浓度>0.3mol/L,自由氯离子浓度只稍微高出浸泡液的氯离子浓度。浸泡后的前63d,自由氯离子浓度随浸泡时间增加逐渐增加,随后,自由氯离子浓度开始随浸泡时间增加而降低。孔溶液中氯离子浓度随养护时间增加而减少。浸泡温度和压滤压力对自由氯离子浓缩没有太大的影响。双电层和试样孔结构压滤前后变化是水泥基材料孔溶液中的自由氯离子浓度升高的主要原因。

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