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高温高压下γ-Si3N4的相变

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Abstract:

为了研究γ-Si3N4在高温高压下的相变,在压力为5.2、5.4及5.7GPa,温度为1300~1450K,保温时间为15min条件下,以Y2O3、Al2O3和La2O3为烧结助剂,制备了γ-Si3N4烧结体。用X射线衍射和扫描电子显微镜对烧结样品进行了分析和观察。结果表明γ-Si3N4首先转变为α-Si3N4,再由α-Si3N4转变为β-Si3N4;β-Si3N4烧结体主要由长柱状的晶粒组成,晶粒相互连接,呈交叉分布,显微结构较为均匀,结构致密。拟合了三相相界方程,得到了γ、γ+α、α、α+β、β-Si3N4相界方程,并讨论了相关的相变机制。

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